Bis(1H-benzotriazole-7-sulfonato-κO)bis(1,10-phenanthroline-κ2 N,N′)cadmium dihydrate
In the title complex, [Cd(C6H4N3O3S)2(C12H8N2)2]·2H2O, the Cd2+ cation is located on an inversion center and is coordinated by four N atoms from two symmetry-related 1,10-phenanthroline ligands and two sulfonate O atoms from two benzotriazole-7-sulfonate anions, displaying a distorted CdN4O2 octahe...
| Main Authors: | , |
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| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238623/ |
| Summary: | In the title complex, [Cd(C6H4N3O3S)2(C12H8N2)2]·2H2O, the Cd2+ cation is located on an inversion center and is coordinated by four N atoms from two symmetry-related 1,10-phenanthroline ligands and two sulfonate O atoms from two benzotriazole-7-sulfonate anions, displaying a distorted CdN4O2 octahedral geometry. In the crystal, O—H⋯N, O—H⋯O, N—H⋯O, C—H⋯N and C—H⋯O hydrogen bonds occur. The lattice water molecules and sulfonate O atoms as donor or acceptor atoms play important roles in the formation of these interactions. |
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