{5,10,15,20-Tetra­kis[4-(oct­yloxy)phen­yl]porphyrinato}copper(II)

{5,10,15,20-Tetra­kis[4-(oct­yloxy)phen­yl]porphyrinato}copper(II)

In the title compound, [Cu(C76H92N4O4)], the central Cu(II) ion is situated on an inversion centre. The porphyrinate core exhibits a nearly planar conformation [maximum deviation = 0.027 (3) Å], with Cu—N distances of 1.997 (2) and 2.001 (2) Å. The benzene rings of the 4-octyloxyphenyl groups are ro...

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Main Authors: Yang, De-Liang, Zhao, Hong-Bin, Liao, Jun-Xu, Chen, Liang, Wang, Bang-Ying
Format: Online
Language:English
Published: International Union of Crystallography 2011
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238604/
id pubmed-3238604
recordtype oai_dc
spelling pubmed-32386042011-12-23 {5,10,15,20-Tetra­kis[4-(oct­yloxy)phen­yl]porphyrinato}copper(II) Yang, De-Liang Zhao, Hong-Bin Liao, Jun-Xu Chen, Liang Wang, Bang-Ying Metal-Organic Papers In the title compound, [Cu(C76H92N4O4)], the central Cu(II) ion is situated on an inversion centre. The porphyrinate core exhibits a nearly planar conformation [maximum deviation = 0.027 (3) Å], with Cu—N distances of 1.997 (2) and 2.001 (2) Å. The benzene rings of the 4-octyloxyphenyl groups are rotated at angles of 84.02 (8) and 77.02 (6)° with respect to the mean plane of the porphyrin fragment. The two terminal C atoms in the octyl group are disordered over two positions of equal occupancy. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238604/ /pubmed/22199495 http://dx.doi.org/10.1107/S1600536811043698 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Yang, De-Liang
Zhao, Hong-Bin
Liao, Jun-Xu
Chen, Liang
Wang, Bang-Ying
spellingShingle Yang, De-Liang
Zhao, Hong-Bin
Liao, Jun-Xu
Chen, Liang
Wang, Bang-Ying
{5,10,15,20-Tetra­kis[4-(oct­yloxy)phen­yl]porphyrinato}copper(II)
author_facet Yang, De-Liang
Zhao, Hong-Bin
Liao, Jun-Xu
Chen, Liang
Wang, Bang-Ying
author_sort Yang, De-Liang
title {5,10,15,20-Tetra­kis[4-(oct­yloxy)phen­yl]porphyrinato}copper(II)
title_short {5,10,15,20-Tetra­kis[4-(oct­yloxy)phen­yl]porphyrinato}copper(II)
title_full {5,10,15,20-Tetra­kis[4-(oct­yloxy)phen­yl]porphyrinato}copper(II)
title_fullStr {5,10,15,20-Tetra­kis[4-(oct­yloxy)phen­yl]porphyrinato}copper(II)
title_full_unstemmed {5,10,15,20-Tetra­kis[4-(oct­yloxy)phen­yl]porphyrinato}copper(II)
title_sort {5,10,15,20-tetra­kis[4-(oct­yloxy)phen­yl]porphyrinato}copper(ii)
description In the title compound, [Cu(C76H92N4O4)], the central Cu(II) ion is situated on an inversion centre. The porphyrinate core exhibits a nearly planar conformation [maximum deviation = 0.027 (3) Å], with Cu—N distances of 1.997 (2) and 2.001 (2) Å. The benzene rings of the 4-octyloxyphenyl groups are rotated at angles of 84.02 (8) and 77.02 (6)° with respect to the mean plane of the porphyrin fragment. The two terminal C atoms in the octyl group are disordered over two positions of equal occupancy.
publisher International Union of Crystallography
publishDate 2011
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238604/
_version_ 1611494240691421184

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