{μ-N,N,N′,N′-Tetra­kis[(diphenyl­phosphan­yl)meth­yl]benzene-1,4-diamine}­bis­[(2,2′-bipyrid­yl)copper(I)] bis­(tetra­fluoridoborate)

{μ-N,N,N′,N′-Tetra­kis[(diphenyl­phosphan­yl)meth­yl]benzene-1,4-diamine}­bis­[(2,2′-bipyrid­yl)copper(I)] bis­(tetra­fluoridoborate)

In the title compound, [Cu2(C10H8N2)2(C58H52N2P4)](BF4)2, the dinuclear cation lies on an inversion centre. The CuI atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and two P atoms from an N,N,N′,N′-tetra­kis­[(diphenyl­phos­phan­yl)meth­yl]benzene-1,4-diamine ligand in a distorted t...

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Main Authors: Luo, Lun-Zhong, Yang, Zong-Wei, Wang, Zhi-Bin, Hong, Zhang
Format: Online
Language:English
Published: International Union of Crystallography 2011
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212203/
id pubmed-3212203
recordtype oai_dc
spelling pubmed-32122032011-11-16 {μ-N,N,N′,N′-Tetra­kis[(diphenyl­phosphan­yl)meth­yl]benzene-1,4-diamine}­bis­[(2,2′-bipyrid­yl)copper(I)] bis­(tetra­fluoridoborate) Luo, Lun-Zhong Yang, Zong-Wei Wang, Zhi-Bin Hong, Zhang Metal-Organic Papers In the title compound, [Cu2(C10H8N2)2(C58H52N2P4)](BF4)2, the dinuclear cation lies on an inversion centre. The CuI atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and two P atoms from an N,N,N′,N′-tetra­kis­[(diphenyl­phos­phan­yl)meth­yl]benzene-1,4-diamine ligand in a distorted tetra­hedral geometry. In the crystal, inter­molecular C—H⋯F hydrogen bonds link the ions into layers parallel to [01]. π–π inter­actions [centroid–centroid distance = 3.668 (4) Å] are also observed. One F atom of the anion is disordered over two orientations with a refined occupancy ratio of 0.675 (13):0.325 (13). International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212203/ /pubmed/22090905 http://dx.doi.org/10.1107/S1600536811029333 Text en © Luo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Luo, Lun-Zhong
Yang, Zong-Wei
Wang, Zhi-Bin
Hong, Zhang
spellingShingle Luo, Lun-Zhong
Yang, Zong-Wei
Wang, Zhi-Bin
Hong, Zhang
{μ-N,N,N′,N′-Tetra­kis[(diphenyl­phosphan­yl)meth­yl]benzene-1,4-diamine}­bis­[(2,2′-bipyrid­yl)copper(I)] bis­(tetra­fluoridoborate)
author_facet Luo, Lun-Zhong
Yang, Zong-Wei
Wang, Zhi-Bin
Hong, Zhang
author_sort Luo, Lun-Zhong
title {μ-N,N,N′,N′-Tetra­kis[(diphenyl­phosphan­yl)meth­yl]benzene-1,4-diamine}­bis­[(2,2′-bipyrid­yl)copper(I)] bis­(tetra­fluoridoborate)
title_short {μ-N,N,N′,N′-Tetra­kis[(diphenyl­phosphan­yl)meth­yl]benzene-1,4-diamine}­bis­[(2,2′-bipyrid­yl)copper(I)] bis­(tetra­fluoridoborate)
title_full {μ-N,N,N′,N′-Tetra­kis[(diphenyl­phosphan­yl)meth­yl]benzene-1,4-diamine}­bis­[(2,2′-bipyrid­yl)copper(I)] bis­(tetra­fluoridoborate)
title_fullStr {μ-N,N,N′,N′-Tetra­kis[(diphenyl­phosphan­yl)meth­yl]benzene-1,4-diamine}­bis­[(2,2′-bipyrid­yl)copper(I)] bis­(tetra­fluoridoborate)
title_full_unstemmed {μ-N,N,N′,N′-Tetra­kis[(diphenyl­phosphan­yl)meth­yl]benzene-1,4-diamine}­bis­[(2,2′-bipyrid­yl)copper(I)] bis­(tetra­fluoridoborate)
title_sort {μ-n,n,n′,n′-tetra­kis[(diphenyl­phosphan­yl)meth­yl]benzene-1,4-diamine}­bis­[(2,2′-bipyrid­yl)copper(i)] bis­(tetra­fluoridoborate)
description In the title compound, [Cu2(C10H8N2)2(C58H52N2P4)](BF4)2, the dinuclear cation lies on an inversion centre. The CuI atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and two P atoms from an N,N,N′,N′-tetra­kis­[(diphenyl­phos­phan­yl)meth­yl]benzene-1,4-diamine ligand in a distorted tetra­hedral geometry. In the crystal, inter­molecular C—H⋯F hydrogen bonds link the ions into layers parallel to [01]. π–π inter­actions [centroid–centroid distance = 3.668 (4) Å] are also observed. One F atom of the anion is disordered over two orientations with a refined occupancy ratio of 0.675 (13):0.325 (13).
publisher International Union of Crystallography
publishDate 2011
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212203/
_version_ 1611486420767080448

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