Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN 1]manganese(II) decahydrate
In the title compound, [Mn(C9H6N3O2)2(H2O)4]·10H2O, the MnII ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water molecules in a distorted octahedral geometry. The MnII ion and two coordinated water molecules lie on a twofold rotation axis. The water...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212150/ |
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pubmed-32121502011-11-16 Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN 1]manganese(II) decahydrate Piao, Ying-Ai Xuan, Zhen-Yu Metal-Organic Papers In the title compound, [Mn(C9H6N3O2)2(H2O)4]·10H2O, the MnII ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water molecules in a distorted octahedral geometry. The MnII ion and two coordinated water molecules lie on a twofold rotation axis. The water molecules are involved in O—H⋯N and O—H⋯O hydrogen bonds with the triazole N atoms and carboxylate O atoms, yielding a three-dimensional supramolecular network. π–π interactions between the benzene rings [centroid–centroid distance = 3.836 (9) Å] are observed. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212150/ /pubmed/22090852 http://dx.doi.org/10.1107/S1600536811025335 Text en © Piao and Xuan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Piao, Ying-Ai Xuan, Zhen-Yu |
| spellingShingle |
Piao, Ying-Ai Xuan, Zhen-Yu Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN 1]manganese(II) decahydrate |
| author_facet |
Piao, Ying-Ai Xuan, Zhen-Yu |
| author_sort |
Piao, Ying-Ai |
| title |
Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN
1]manganese(II) decahydrate |
| title_short |
Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN
1]manganese(II) decahydrate |
| title_full |
Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN
1]manganese(II) decahydrate |
| title_fullStr |
Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN
1]manganese(II) decahydrate |
| title_full_unstemmed |
Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN
1]manganese(II) decahydrate |
| title_sort |
tetraaquabis[4-(4h-1,2,4-triazol-4-yl)benzoato-κn
1]manganese(ii) decahydrate |
| description |
In the title compound, [Mn(C9H6N3O2)2(H2O)4]·10H2O, the MnII ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water molecules in a distorted octahedral geometry. The MnII ion and two coordinated water molecules lie on a twofold rotation axis. The water molecules are involved in O—H⋯N and O—H⋯O hydrogen bonds with the triazole N atoms and carboxylate O atoms, yielding a three-dimensional supramolecular network. π–π interactions between the benzene rings [centroid–centroid distance = 3.836 (9) Å] are observed. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212150/ |
| _version_ |
1611486391030513664 |