Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ2 N 3:N 3′](μ-5-methylisophthalato-κ2 O 1:O 3)cobalt(II)]
In the title coordination polymer, [Co(C9H6O4)(C12H10N4)]n, the CoII atom is four-coordinated by two O atoms from two different 5-methylisophthalate bivalent anions and two N atoms from two different 1,4-bis(1H-imidazol-4-yl)benzene ligands, forming a four-coordinated tetrahedral coordination geo...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212123/ |
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pubmed-3212123 |
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oai_dc |
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pubmed-32121232011-11-16 Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ2 N 3:N 3′](μ-5-methylisophthalato-κ2 O 1:O 3)cobalt(II)] Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping Metal-Organic Papers In the title coordination polymer, [Co(C9H6O4)(C12H10N4)]n, the CoII atom is four-coordinated by two O atoms from two different 5-methylisophthalate bivalent anions and two N atoms from two different 1,4-bis(1H-imidazol-4-yl)benzene ligands, forming a four-coordinated tetrahedral coordination geometry. Each 5-methylisophthalate ligand acts as a μ2-bridge, linking two CoII atoms and forming chains which are further linked by 1,4-bis(1H-imidazol-4-yl)benzene ligands into a two-dimensional network parallel to (01). These planes are, in turn, linked by two intermolecular N—H⋯O interactions, forming a three-dimensional structure. Weak C—H⋯O hydrogen bonds are also present in the structure. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212123/ /pubmed/22090825 http://dx.doi.org/10.1107/S1600536811025657 Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping |
| spellingShingle |
Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ2 N 3:N 3′](μ-5-methylisophthalato-κ2 O 1:O 3)cobalt(II)] |
| author_facet |
Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping |
| author_sort |
Chen, Shui-Sheng |
| title |
Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ2
N
3:N
3′](μ-5-methylisophthalato-κ2
O
1:O
3)cobalt(II)] |
| title_short |
Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ2
N
3:N
3′](μ-5-methylisophthalato-κ2
O
1:O
3)cobalt(II)] |
| title_full |
Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ2
N
3:N
3′](μ-5-methylisophthalato-κ2
O
1:O
3)cobalt(II)] |
| title_fullStr |
Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ2
N
3:N
3′](μ-5-methylisophthalato-κ2
O
1:O
3)cobalt(II)] |
| title_full_unstemmed |
Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ2
N
3:N
3′](μ-5-methylisophthalato-κ2
O
1:O
3)cobalt(II)] |
| title_sort |
poly[[μ-1,4-bis(1h-imidazol-4-yl)benzene-κ2
n
3:n
3′](μ-5-methylisophthalato-κ2
o
1:o
3)cobalt(ii)] |
| description |
In the title coordination polymer, [Co(C9H6O4)(C12H10N4)]n, the CoII atom is four-coordinated by two O atoms from two different 5-methylisophthalate bivalent anions and two N atoms from two different 1,4-bis(1H-imidazol-4-yl)benzene ligands, forming a four-coordinated tetrahedral coordination geometry. Each 5-methylisophthalate ligand acts as a μ2-bridge, linking two CoII atoms and forming chains which are further linked by 1,4-bis(1H-imidazol-4-yl)benzene ligands into a two-dimensional network parallel to (01). These planes are, in turn, linked by two intermolecular N—H⋯O interactions, forming a three-dimensional structure. Weak C—H⋯O hydrogen bonds are also present in the structure. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212123/ |
| _version_ |
1611486374942212096 |