catena-Poly[[trimethyltin(IV)]-μ-3,5-difluorobenzoato-κ2 O:O′]
In the title compound, [Sn(CH3)3(C7H3F2O2)]n, the central Sn atom is coordinated by two O atoms from the anion and three methyl C atoms in a polymeric fashion owing to the presence of bidentate bridging carboxylate ligands. The five-coordinate Sn atom exists in a distorted trigonal–bipyramidal geom...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212122/ |
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pubmed-3212122 |
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oai_dc |
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pubmed-32121222011-11-16 catena-Poly[[trimethyltin(IV)]-μ-3,5-difluorobenzoato-κ2 O:O′] Liu, Hong Yin, Handong Metal-Organic Papers In the title compound, [Sn(CH3)3(C7H3F2O2)]n, the central Sn atom is coordinated by two O atoms from the anion and three methyl C atoms in a polymeric fashion owing to the presence of bidentate bridging carboxylate ligands. The five-coordinate Sn atom exists in a distorted trigonal–bipyramidal geometry with the molecules connected by weak C—H⋯F intermoleclar interactions, forming supramolecular chains parallel to [010]. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212122/ /pubmed/22090824 http://dx.doi.org/10.1107/S1600536811025608 Text en © Liu and Yin 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Liu, Hong Yin, Handong |
| spellingShingle |
Liu, Hong Yin, Handong catena-Poly[[trimethyltin(IV)]-μ-3,5-difluorobenzoato-κ2 O:O′] |
| author_facet |
Liu, Hong Yin, Handong |
| author_sort |
Liu, Hong |
| title |
catena-Poly[[trimethyltin(IV)]-μ-3,5-difluorobenzoato-κ2
O:O′] |
| title_short |
catena-Poly[[trimethyltin(IV)]-μ-3,5-difluorobenzoato-κ2
O:O′] |
| title_full |
catena-Poly[[trimethyltin(IV)]-μ-3,5-difluorobenzoato-κ2
O:O′] |
| title_fullStr |
catena-Poly[[trimethyltin(IV)]-μ-3,5-difluorobenzoato-κ2
O:O′] |
| title_full_unstemmed |
catena-Poly[[trimethyltin(IV)]-μ-3,5-difluorobenzoato-κ2
O:O′] |
| title_sort |
catena-poly[[trimethyltin(iv)]-μ-3,5-difluorobenzoato-κ2
o:o′] |
| description |
In the title compound, [Sn(CH3)3(C7H3F2O2)]n, the central Sn atom is coordinated by two O atoms from the anion and three methyl C atoms in a polymeric fashion owing to the presence of bidentate bridging carboxylate ligands. The five-coordinate Sn atom exists in a distorted trigonal–bipyramidal geometry with the molecules connected by weak C—H⋯F intermoleclar interactions, forming supramolecular chains parallel to [010]. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212122/ |
| _version_ |
1611486374336135168 |