Bis(μ-3-chlorobenzene-1,2-dicarboxylato-κ2 O 2:O 2)bis[diaqua(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)copper(II)]
In the centrosymmetric binuclear title compound, [Cu2(C8H3ClO4)2(C12H12N2)2(H2O)4], the CuII ion is six-coordinated by two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, two bridging O atoms from two 3-chlorobenzene-1,2-dicarboxylate ligands and two water molecules in a distorted octahedra...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201524/ |
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pubmed-3201524 |
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oai_dc |
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pubmed-32015242011-11-06 Bis(μ-3-chlorobenzene-1,2-dicarboxylato-κ2 O 2:O 2)bis[diaqua(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)copper(II)] Li, Fu-An Xu, Fu Hu, Xiao-Ming Metal-Organic Papers In the centrosymmetric binuclear title compound, [Cu2(C8H3ClO4)2(C12H12N2)2(H2O)4], the CuII ion is six-coordinated by two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, two bridging O atoms from two 3-chlorobenzene-1,2-dicarboxylate ligands and two water molecules in a distorted octahedral geometry. The binuclear complex molecules are linked together by intermolecular O—H⋯O hydrogen bonds into a layer parallel to (100). The layers are connected by C—H⋯Cl hydrogen bonds. Intramolecular O—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.5958 (16) Å] are also present. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201524/ /pubmed/22058694 http://dx.doi.org/10.1107/S1600536811035112 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Li, Fu-An Xu, Fu Hu, Xiao-Ming |
| spellingShingle |
Li, Fu-An Xu, Fu Hu, Xiao-Ming Bis(μ-3-chlorobenzene-1,2-dicarboxylato-κ2 O 2:O 2)bis[diaqua(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)copper(II)] |
| author_facet |
Li, Fu-An Xu, Fu Hu, Xiao-Ming |
| author_sort |
Li, Fu-An |
| title |
Bis(μ-3-chlorobenzene-1,2-dicarboxylato-κ2
O
2:O
2)bis[diaqua(5,5′-dimethyl-2,2′-bipyridine-κ2
N,N′)copper(II)] |
| title_short |
Bis(μ-3-chlorobenzene-1,2-dicarboxylato-κ2
O
2:O
2)bis[diaqua(5,5′-dimethyl-2,2′-bipyridine-κ2
N,N′)copper(II)] |
| title_full |
Bis(μ-3-chlorobenzene-1,2-dicarboxylato-κ2
O
2:O
2)bis[diaqua(5,5′-dimethyl-2,2′-bipyridine-κ2
N,N′)copper(II)] |
| title_fullStr |
Bis(μ-3-chlorobenzene-1,2-dicarboxylato-κ2
O
2:O
2)bis[diaqua(5,5′-dimethyl-2,2′-bipyridine-κ2
N,N′)copper(II)] |
| title_full_unstemmed |
Bis(μ-3-chlorobenzene-1,2-dicarboxylato-κ2
O
2:O
2)bis[diaqua(5,5′-dimethyl-2,2′-bipyridine-κ2
N,N′)copper(II)] |
| title_sort |
bis(μ-3-chlorobenzene-1,2-dicarboxylato-κ2
o
2:o
2)bis[diaqua(5,5′-dimethyl-2,2′-bipyridine-κ2
n,n′)copper(ii)] |
| description |
In the centrosymmetric binuclear title compound, [Cu2(C8H3ClO4)2(C12H12N2)2(H2O)4], the CuII ion is six-coordinated by two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, two bridging O atoms from two 3-chlorobenzene-1,2-dicarboxylate ligands and two water molecules in a distorted octahedral geometry. The binuclear complex molecules are linked together by intermolecular O—H⋯O hydrogen bonds into a layer parallel to (100). The layers are connected by C—H⋯Cl hydrogen bonds. Intramolecular O—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.5958 (16) Å] are also present. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201524/ |
| _version_ |
1611483683661807616 |