Poly[[diaquabis(2,2′-bipyridine-κ2 N,N′)(μ3-5-hydroxyisophthalato-κ5 O 1,O 1′:O 3,O 3′:O 3′)(μ3-5-hydroxyisophthalato-κ4 O 1,O 1′:O 3:O 3′)(μ2-5-hydroxyisophthalato-κ3 O 1,O 1′:O 3)didysprosium(III)] dihydrate]
The polymeric title compound, {[Dy2(C8H4O5)3(C10H8N2)2(H2O)2]·2H2O}n, contains two independent DyIII ions, both of which are nine-coordinated in a distorted tricapped trigonal–prismatic geometry. One DyIII ion is coordinated by five 5-hydroxyisophthalate (hip) ligands and one 2,2′-bipyridine (bpy)...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201354/ |
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pubmed-3201354 |
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oai_dc |
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pubmed-32013542011-11-06 Poly[[diaquabis(2,2′-bipyridine-κ2 N,N′)(μ3-5-hydroxyisophthalato-κ5 O 1,O 1′:O 3,O 3′:O 3′)(μ3-5-hydroxyisophthalato-κ4 O 1,O 1′:O 3:O 3′)(μ2-5-hydroxyisophthalato-κ3 O 1,O 1′:O 3)didysprosium(III)] dihydrate] Zhang, Yan-Lin Metal-Organic Papers The polymeric title compound, {[Dy2(C8H4O5)3(C10H8N2)2(H2O)2]·2H2O}n, contains two independent DyIII ions, both of which are nine-coordinated in a distorted tricapped trigonal–prismatic geometry. One DyIII ion is coordinated by five 5-hydroxyisophthalate (hip) ligands and one 2,2′-bipyridine (bpy) ligand and the other by three hip ligands, one bpy ligand and two water molecules. The DyIII ions are bridged by the carboxylate groups of the hip ligands, forming a three-dimensional framework. O—H⋯O hydrogen bonds are present in the crystal structure. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201354/ /pubmed/22058725 http://dx.doi.org/10.1107/S1600536811039080 Text en © Yan-Lin Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Zhang, Yan-Lin |
| spellingShingle |
Zhang, Yan-Lin Poly[[diaquabis(2,2′-bipyridine-κ2 N,N′)(μ3-5-hydroxyisophthalato-κ5 O 1,O 1′:O 3,O 3′:O 3′)(μ3-5-hydroxyisophthalato-κ4 O 1,O 1′:O 3:O 3′)(μ2-5-hydroxyisophthalato-κ3 O 1,O 1′:O 3)didysprosium(III)] dihydrate] |
| author_facet |
Zhang, Yan-Lin |
| author_sort |
Zhang, Yan-Lin |
| title |
Poly[[diaquabis(2,2′-bipyridine-κ2
N,N′)(μ3-5-hydroxyisophthalato-κ5
O
1,O
1′:O
3,O
3′:O
3′)(μ3-5-hydroxyisophthalato-κ4
O
1,O
1′:O
3:O
3′)(μ2-5-hydroxyisophthalato-κ3
O
1,O
1′:O
3)didysprosium(III)] dihydrate] |
| title_short |
Poly[[diaquabis(2,2′-bipyridine-κ2
N,N′)(μ3-5-hydroxyisophthalato-κ5
O
1,O
1′:O
3,O
3′:O
3′)(μ3-5-hydroxyisophthalato-κ4
O
1,O
1′:O
3:O
3′)(μ2-5-hydroxyisophthalato-κ3
O
1,O
1′:O
3)didysprosium(III)] dihydrate] |
| title_full |
Poly[[diaquabis(2,2′-bipyridine-κ2
N,N′)(μ3-5-hydroxyisophthalato-κ5
O
1,O
1′:O
3,O
3′:O
3′)(μ3-5-hydroxyisophthalato-κ4
O
1,O
1′:O
3:O
3′)(μ2-5-hydroxyisophthalato-κ3
O
1,O
1′:O
3)didysprosium(III)] dihydrate] |
| title_fullStr |
Poly[[diaquabis(2,2′-bipyridine-κ2
N,N′)(μ3-5-hydroxyisophthalato-κ5
O
1,O
1′:O
3,O
3′:O
3′)(μ3-5-hydroxyisophthalato-κ4
O
1,O
1′:O
3:O
3′)(μ2-5-hydroxyisophthalato-κ3
O
1,O
1′:O
3)didysprosium(III)] dihydrate] |
| title_full_unstemmed |
Poly[[diaquabis(2,2′-bipyridine-κ2
N,N′)(μ3-5-hydroxyisophthalato-κ5
O
1,O
1′:O
3,O
3′:O
3′)(μ3-5-hydroxyisophthalato-κ4
O
1,O
1′:O
3:O
3′)(μ2-5-hydroxyisophthalato-κ3
O
1,O
1′:O
3)didysprosium(III)] dihydrate] |
| title_sort |
poly[[diaquabis(2,2′-bipyridine-κ2
n,n′)(μ3-5-hydroxyisophthalato-κ5
o
1,o
1′:o
3,o
3′:o
3′)(μ3-5-hydroxyisophthalato-κ4
o
1,o
1′:o
3:o
3′)(μ2-5-hydroxyisophthalato-κ3
o
1,o
1′:o
3)didysprosium(iii)] dihydrate] |
| description |
The polymeric title compound, {[Dy2(C8H4O5)3(C10H8N2)2(H2O)2]·2H2O}n, contains two independent DyIII ions, both of which are nine-coordinated in a distorted tricapped trigonal–prismatic geometry. One DyIII ion is coordinated by five 5-hydroxyisophthalate (hip) ligands and one 2,2′-bipyridine (bpy) ligand and the other by three hip ligands, one bpy ligand and two water molecules. The DyIII ions are bridged by the carboxylate groups of the hip ligands, forming a three-dimensional framework. O—H⋯O hydrogen bonds are present in the crystal structure. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201354/ |
| _version_ |
1611483584143556608 |