catena-Poly[[aqua[1,4-bis(1H-imidazol-4-yl)benzene]cadmium]-μ3-5-methylisophthalato]
In the title coordination polymer, [Cd(C9H6O4)(C12H10N4)(H2O)]n, the CdII atom has a NO6 donor set and is coordinated by five carboxylate O atoms from three different 5-methyl-1,3-phenylenediacetate (pda2−) anions, one O atom from a water molecule and one N atom from a 1,4-bis(1H-imidazol-4-yl)...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200974/ |
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pubmed-3200974 |
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oai_dc |
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pubmed-32009742011-11-06 catena-Poly[[aqua[1,4-bis(1H-imidazol-4-yl)benzene]cadmium]-μ3-5-methylisophthalato] Yang, Sen-Lin Wang, De-Hai Chen, Shui-Sheng Metal-Organic Papers In the title coordination polymer, [Cd(C9H6O4)(C12H10N4)(H2O)]n, the CdII atom has a NO6 donor set and is coordinated by five carboxylate O atoms from three different 5-methyl-1,3-phenylenediacetate (pda2−) anions, one O atom from a water molecule and one N atom from a 1,4-bis(1H-imidazol-4-yl)benzene (L) ligand, displaying a highly distorted pentagonal–bipyramidal geometry. Each pda2− anion acts as a μ3-bridge, linking CdII atoms to form one-dimensional slabs extending parallel to [010]. In the crystal, adjacent molecules are linked through N—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200974/ /pubmed/22065019 http://dx.doi.org/10.1107/S1600536811030509 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Yang, Sen-Lin Wang, De-Hai Chen, Shui-Sheng |
| spellingShingle |
Yang, Sen-Lin Wang, De-Hai Chen, Shui-Sheng catena-Poly[[aqua[1,4-bis(1H-imidazol-4-yl)benzene]cadmium]-μ3-5-methylisophthalato] |
| author_facet |
Yang, Sen-Lin Wang, De-Hai Chen, Shui-Sheng |
| author_sort |
Yang, Sen-Lin |
| title |
catena-Poly[[aqua[1,4-bis(1H-imidazol-4-yl)benzene]cadmium]-μ3-5-methylisophthalato] |
| title_short |
catena-Poly[[aqua[1,4-bis(1H-imidazol-4-yl)benzene]cadmium]-μ3-5-methylisophthalato] |
| title_full |
catena-Poly[[aqua[1,4-bis(1H-imidazol-4-yl)benzene]cadmium]-μ3-5-methylisophthalato] |
| title_fullStr |
catena-Poly[[aqua[1,4-bis(1H-imidazol-4-yl)benzene]cadmium]-μ3-5-methylisophthalato] |
| title_full_unstemmed |
catena-Poly[[aqua[1,4-bis(1H-imidazol-4-yl)benzene]cadmium]-μ3-5-methylisophthalato] |
| title_sort |
catena-poly[[aqua[1,4-bis(1h-imidazol-4-yl)benzene]cadmium]-μ3-5-methylisophthalato] |
| description |
In the title coordination polymer, [Cd(C9H6O4)(C12H10N4)(H2O)]n, the CdII atom has a NO6 donor set and is coordinated by five carboxylate O atoms from three different 5-methyl-1,3-phenylenediacetate (pda2−) anions, one O atom from a water molecule and one N atom from a 1,4-bis(1H-imidazol-4-yl)benzene (L) ligand, displaying a highly distorted pentagonal–bipyramidal geometry. Each pda2− anion acts as a μ3-bridge, linking CdII atoms to form one-dimensional slabs extending parallel to [010]. In the crystal, adjacent molecules are linked through N—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200974/ |
| _version_ |
1611483417273171968 |