catena-Poly[[diaquacopper(II)]-μ-hydroxido-κ2 O:O-μ-[4-(4H-1,2,4-triazol-4-yl)benzoato]-κ2 N 1:N 2]
The title compound, [Cu(C9H6N3O2)(OH)(H2O)2]n, adopts a chain motif along [010] in which the CuII atoms are bridged by hydroxy groups and 4-(1,2,4-triazol-4-yl)benzoate (tab) ligands. The CuII atom lies on an inversion center and is six-coordinated by two N atoms from two tab ligands, two hydroxy...
| Main Authors: | , , |
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| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200671/ |
| Summary: | The title compound, [Cu(C9H6N3O2)(OH)(H2O)2]n, adopts a chain motif along [010] in which the CuII atoms are bridged by hydroxy groups and 4-(1,2,4-triazol-4-yl)benzoate (tab) ligands. The CuII atom lies on an inversion center and is six-coordinated by two N atoms from two tab ligands, two hydroxy groups and two water molecules, giving a distorted octahedral geometry. The hydroxy group and the tab ligand are located on a mirror plane. One of the water H atoms is disordered over two positions with equal occupancy factors. Intermolecular O—H⋯O hydrogen bonds extend the chains into a layer parallel to (100) and C—H⋯O hydrogen bonds connect the layers into a three-dimensional network. |
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