[6-(4-Bromophenyl)-2,2′-bipyridine-κ2 N,N′]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate
The title compound, [Cu(C16H11BrN2)(C18H15P)2]BF4, is composed of one CuI atom, one 6-(4-bromophenyl)-2,2′-bipyridine (L) ligand, two triphenylphosphane molecules and one tetrafluoridoborate anion. The CuI ion is four-coordinated in a distorted tetrahedral configuration by two N atoms from L a...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200642/ |
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pubmed-32006422011-11-06 [6-(4-Bromophenyl)-2,2′-bipyridine-κ2 N,N′]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate Lin, Yan-Ru Huang, Jun-Sheng Zhong, Ming-Hua Metal-Organic Papers The title compound, [Cu(C16H11BrN2)(C18H15P)2]BF4, is composed of one CuI atom, one 6-(4-bromophenyl)-2,2′-bipyridine (L) ligand, two triphenylphosphane molecules and one tetrafluoridoborate anion. The CuI ion is four-coordinated in a distorted tetrahedral configuration by two N atoms from L and two P atoms from triphenylphosphane ligands. In the L ligand, the two pyridine rings are not coplanar; the mean planes making a dihedral angle of 15.3 (5)°. In the crystal, the ions are linked by weak C—H⋯F interactions. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200642/ /pubmed/22058839 http://dx.doi.org/10.1107/S1600536811029515 Text en © Lin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Lin, Yan-Ru Huang, Jun-Sheng Zhong, Ming-Hua |
| spellingShingle |
Lin, Yan-Ru Huang, Jun-Sheng Zhong, Ming-Hua [6-(4-Bromophenyl)-2,2′-bipyridine-κ2 N,N′]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate |
| author_facet |
Lin, Yan-Ru Huang, Jun-Sheng Zhong, Ming-Hua |
| author_sort |
Lin, Yan-Ru |
| title |
[6-(4-Bromophenyl)-2,2′-bipyridine-κ2
N,N′]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate |
| title_short |
[6-(4-Bromophenyl)-2,2′-bipyridine-κ2
N,N′]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate |
| title_full |
[6-(4-Bromophenyl)-2,2′-bipyridine-κ2
N,N′]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate |
| title_fullStr |
[6-(4-Bromophenyl)-2,2′-bipyridine-κ2
N,N′]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate |
| title_full_unstemmed |
[6-(4-Bromophenyl)-2,2′-bipyridine-κ2
N,N′]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate |
| title_sort |
[6-(4-bromophenyl)-2,2′-bipyridine-κ2
n,n′]bis(triphenylphosphane-κp)copper(i) tetrafluoridoborate |
| description |
The title compound, [Cu(C16H11BrN2)(C18H15P)2]BF4, is composed of one CuI atom, one 6-(4-bromophenyl)-2,2′-bipyridine (L) ligand, two triphenylphosphane molecules and one tetrafluoridoborate anion. The CuI ion is four-coordinated in a distorted tetrahedral configuration by two N atoms from L and two P atoms from triphenylphosphane ligands. In the L ligand, the two pyridine rings are not coplanar; the mean planes making a dihedral angle of 15.3 (5)°. In the crystal, the ions are linked by weak C—H⋯F interactions. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200642/ |
| _version_ |
1611483222090186752 |