Poly[[aquatris(μ-benzene-1,4-dicarboxylato)tricobalt(II)] methanol monosolvate monohydrate]
The asymmetric unit of the title compound, {[Co3(C8H4O4)3(H2O)]·CH3OH·H2O}n, consists of four crystallographically independent Co cations, four benzene-1,4-dicarboxylate (bdc) anions, two water and one methanol solvent molecule. Two of the Co cations and two of the bdc anions are located on centre...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152069/ |
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pubmed-3152069 |
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oai_dc |
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pubmed-31520692011-08-11 Poly[[aquatris(μ-benzene-1,4-dicarboxylato)tricobalt(II)] methanol monosolvate monohydrate] Zhou, Hu Chu, Chao-Xia Li, Yi-Zhi Metal-Organic Papers The asymmetric unit of the title compound, {[Co3(C8H4O4)3(H2O)]·CH3OH·H2O}n, consists of four crystallographically independent Co cations, four benzene-1,4-dicarboxylate (bdc) anions, two water and one methanol solvent molecule. Two of the Co cations and two of the bdc anions are located on centres of inversion, whereas all other atoms are located in general positions. In the crystal, two Co atoms are only fourfold coordinated by three O atoms from three bdc ligands and by one O atom from one coordinated water molecule, while a third Co atom is coordinated by four O atoms from four bdc ligands within a strongly distorted tetrahedral geometry. The other two Co cations are octahedrally coordinated by six O atoms from six bdc anions. The Co cations are linked by the bdc anions into a three-dimensional framework. From this arrangement, cavities are formed in which additional methanol and water molecules are embedded. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3152069/ /pubmed/21836846 http://dx.doi.org/10.1107/S1600536811020009 Text en © Zhou et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Zhou, Hu Chu, Chao-Xia Li, Yi-Zhi |
| spellingShingle |
Zhou, Hu Chu, Chao-Xia Li, Yi-Zhi Poly[[aquatris(μ-benzene-1,4-dicarboxylato)tricobalt(II)] methanol monosolvate monohydrate] |
| author_facet |
Zhou, Hu Chu, Chao-Xia Li, Yi-Zhi |
| author_sort |
Zhou, Hu |
| title |
Poly[[aquatris(μ-benzene-1,4-dicarboxylato)tricobalt(II)] methanol monosolvate monohydrate] |
| title_short |
Poly[[aquatris(μ-benzene-1,4-dicarboxylato)tricobalt(II)] methanol monosolvate monohydrate] |
| title_full |
Poly[[aquatris(μ-benzene-1,4-dicarboxylato)tricobalt(II)] methanol monosolvate monohydrate] |
| title_fullStr |
Poly[[aquatris(μ-benzene-1,4-dicarboxylato)tricobalt(II)] methanol monosolvate monohydrate] |
| title_full_unstemmed |
Poly[[aquatris(μ-benzene-1,4-dicarboxylato)tricobalt(II)] methanol monosolvate monohydrate] |
| title_sort |
poly[[aquatris(μ-benzene-1,4-dicarboxylato)tricobalt(ii)] methanol monosolvate monohydrate] |
| description |
The asymmetric unit of the title compound, {[Co3(C8H4O4)3(H2O)]·CH3OH·H2O}n, consists of four crystallographically independent Co cations, four benzene-1,4-dicarboxylate (bdc) anions, two water and one methanol solvent molecule. Two of the Co cations and two of the bdc anions are located on centres of inversion, whereas all other atoms are located in general positions. In the crystal, two Co atoms are only fourfold coordinated by three O atoms from three bdc ligands and by one O atom from one coordinated water molecule, while a third Co atom is coordinated by four O atoms from four bdc ligands within a strongly distorted tetrahedral geometry. The other two Co cations are octahedrally coordinated by six O atoms from six bdc anions. The Co cations are linked by the bdc anions into a three-dimensional framework. From this arrangement, cavities are formed in which additional methanol and water molecules are embedded. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152069/ |
| _version_ |
1611469671590002688 |