Di-μ-benzoato-κ3 O,O′:O′;κ3 O:O,O′-bis[(benzoato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)cadmium]
The dinuclear title compound, [Cd2(C7H5O2)4(C12H8N2)2], lies on a crystallographic twofold axis. The CdII ions are connected by two bridging benzoate anions and each ion is seven-coordinated by five O atoms from three benzoate ligands and by two N atoms from 1,10-phenanthroline. The benzoate ligands...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151832/ |
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pubmed-3151832 |
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oai_dc |
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pubmed-31518322011-08-11 Di-μ-benzoato-κ3 O,O′:O′;κ3 O:O,O′-bis[(benzoato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)cadmium] Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong Metal-Organic Papers The dinuclear title compound, [Cd2(C7H5O2)4(C12H8N2)2], lies on a crystallographic twofold axis. The CdII ions are connected by two bridging benzoate anions and each ion is seven-coordinated by five O atoms from three benzoate ligands and by two N atoms from 1,10-phenanthroline. The benzoate ligands adopt two different coordination modes, acting as bidentate and bridging tridentate ligands. The discrete neutral molecules further extend their structure into a three-dimensional supramolecular framework by intermolecular π–π [interplanar distances of 3.392 (4) Å] and C—H⋯π stacking interactions [H–mean plane = 2.567 (4) and 2.781 (4) Å]. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151832/ /pubmed/21836904 http://dx.doi.org/10.1107/S1600536811022185 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong |
| spellingShingle |
Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong Di-μ-benzoato-κ3 O,O′:O′;κ3 O:O,O′-bis[(benzoato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)cadmium] |
| author_facet |
Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong |
| author_sort |
Li, Hong-Jin |
| title |
Di-μ-benzoato-κ3
O,O′:O′;κ3
O:O,O′-bis[(benzoato-κ2
O,O′)(1,10-phenanthroline-κ2
N,N′)cadmium] |
| title_short |
Di-μ-benzoato-κ3
O,O′:O′;κ3
O:O,O′-bis[(benzoato-κ2
O,O′)(1,10-phenanthroline-κ2
N,N′)cadmium] |
| title_full |
Di-μ-benzoato-κ3
O,O′:O′;κ3
O:O,O′-bis[(benzoato-κ2
O,O′)(1,10-phenanthroline-κ2
N,N′)cadmium] |
| title_fullStr |
Di-μ-benzoato-κ3
O,O′:O′;κ3
O:O,O′-bis[(benzoato-κ2
O,O′)(1,10-phenanthroline-κ2
N,N′)cadmium] |
| title_full_unstemmed |
Di-μ-benzoato-κ3
O,O′:O′;κ3
O:O,O′-bis[(benzoato-κ2
O,O′)(1,10-phenanthroline-κ2
N,N′)cadmium] |
| title_sort |
di-μ-benzoato-κ3
o,o′:o′;κ3
o:o,o′-bis[(benzoato-κ2
o,o′)(1,10-phenanthroline-κ2
n,n′)cadmium] |
| description |
The dinuclear title compound, [Cd2(C7H5O2)4(C12H8N2)2], lies on a crystallographic twofold axis. The CdII ions are connected by two bridging benzoate anions and each ion is seven-coordinated by five O atoms from three benzoate ligands and by two N atoms from 1,10-phenanthroline. The benzoate ligands adopt two different coordination modes, acting as bidentate and bridging tridentate ligands. The discrete neutral molecules further extend their structure into a three-dimensional supramolecular framework by intermolecular π–π [interplanar distances of 3.392 (4) Å] and C—H⋯π stacking interactions [H–mean plane = 2.567 (4) and 2.781 (4) Å]. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151832/ |
| _version_ |
1611469531261173760 |