Bis(2-amino-6-methyl-1,3-benzothia­zole-κN 3)bis­(4-nitro­benzoato-κO 1)zinc

In the title mononuclear complex, [Zn(C7H4NO4)2(C8H8N2S)2], the ZnII atom is coordinated by two N atoms from two 2-amino-6-methyl-1,3-benzothia­zole and by two carboxylate O atoms from two 4-nitro­benzoate ligands, adopting a slightly distorted tetra­hedral coordination geometry. In the crystal, int...

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Main Authors: Sun, Xue-Tong, Wang, Xiu-Guang, Zhao, Xiao-Jun
Format: Online
Language:English
Published: International Union of Crystallography 2011
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151824/
id pubmed-3151824
recordtype oai_dc
spelling pubmed-31518242011-08-11 Bis(2-amino-6-methyl-1,3-benzothia­zole-κN 3)bis­(4-nitro­benzoato-κO 1)zinc Sun, Xue-Tong Wang, Xiu-Guang Zhao, Xiao-Jun Metal-Organic Papers In the title mononuclear complex, [Zn(C7H4NO4)2(C8H8N2S)2], the ZnII atom is coordinated by two N atoms from two 2-amino-6-methyl-1,3-benzothia­zole and by two carboxylate O atoms from two 4-nitro­benzoate ligands, adopting a slightly distorted tetra­hedral coordination geometry. In the crystal, inter­molecular N—H⋯O hydrogen bonds between the amino group of 2-amino-6-methyl-1,3-benzothia­zole and the carboxyl­ate group of 4-nitro­benzoate link these discrete mononuclear units into a one-dimensional supra­molecular chain extending parallel to [100]. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151824/ /pubmed/21836917 http://dx.doi.org/10.1107/S1600536811022331 Text en © Sun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Sun, Xue-Tong
Wang, Xiu-Guang
Zhao, Xiao-Jun
spellingShingle Sun, Xue-Tong
Wang, Xiu-Guang
Zhao, Xiao-Jun
Bis(2-amino-6-methyl-1,3-benzothia­zole-κN 3)bis­(4-nitro­benzoato-κO 1)zinc
author_facet Sun, Xue-Tong
Wang, Xiu-Guang
Zhao, Xiao-Jun
author_sort Sun, Xue-Tong
title Bis(2-amino-6-methyl-1,3-benzothia­zole-κN 3)bis­(4-nitro­benzoato-κO 1)zinc
title_short Bis(2-amino-6-methyl-1,3-benzothia­zole-κN 3)bis­(4-nitro­benzoato-κO 1)zinc
title_full Bis(2-amino-6-methyl-1,3-benzothia­zole-κN 3)bis­(4-nitro­benzoato-κO 1)zinc
title_fullStr Bis(2-amino-6-methyl-1,3-benzothia­zole-κN 3)bis­(4-nitro­benzoato-κO 1)zinc
title_full_unstemmed Bis(2-amino-6-methyl-1,3-benzothia­zole-κN 3)bis­(4-nitro­benzoato-κO 1)zinc
title_sort bis(2-amino-6-methyl-1,3-benzothia­zole-κn 3)bis­(4-nitro­benzoato-κo 1)zinc
description In the title mononuclear complex, [Zn(C7H4NO4)2(C8H8N2S)2], the ZnII atom is coordinated by two N atoms from two 2-amino-6-methyl-1,3-benzothia­zole and by two carboxylate O atoms from two 4-nitro­benzoate ligands, adopting a slightly distorted tetra­hedral coordination geometry. In the crystal, inter­molecular N—H⋯O hydrogen bonds between the amino group of 2-amino-6-methyl-1,3-benzothia­zole and the carboxyl­ate group of 4-nitro­benzoate link these discrete mononuclear units into a one-dimensional supra­molecular chain extending parallel to [100].
publisher International Union of Crystallography
publishDate 2011
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151824/
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