catena-Poly[[[tetrakis(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ4 C:N-bis[diaqua(2,2′-bipyridyl-κ2 N,N′)manganese(II)]-di-μ-cyanido-κ4 N:C] hexahydrate]
The polymeric title compound, {[MnII 2WIV(CN)8(C10H8N2)2(H2O)4]·6H2O}n, has a one-dimensional cyanide-bridged MnII–WIV bimetallic assembly. The coordination geometry of the WIV atom is eight-coordinate square-antiprismatic and that of each of the MnII atoms is six-coordinate distorte...
| Main Authors: | , , , |
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| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120535/ |