Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)]
The asymmetric unit of the title compound, [Cu2(C12H9N2O)2(C7H5O2)2], contains two independent (2-formylphenolato){2-[(pyridin-2-yl)iminomethyl]phenolato}copper(II) molecules that form pseudocentrosymmetric dimers via interactions between the Cu and pyridyl N atoms of independent monomers. The...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120375/ |
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pubmed-3120375 |
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oai_dc |
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pubmed-31203752011-07-13 Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)] Chang, Hui-Chang Cole, Jacqueline M. Lin, Tze-Chia Sylvester, Sven O. Waddell, Paul G. Metal-Organic Papers The asymmetric unit of the title compound, [Cu2(C12H9N2O)2(C7H5O2)2], contains two independent (2-formylphenolato){2-[(pyridin-2-yl)iminomethyl]phenolato}copper(II) molecules that form pseudocentrosymmetric dimers via interactions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17). International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120375/ /pubmed/21754595 http://dx.doi.org/10.1107/S1600536811015674 Text en © Chang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Chang, Hui-Chang Cole, Jacqueline M. Lin, Tze-Chia Sylvester, Sven O. Waddell, Paul G. |
| spellingShingle |
Chang, Hui-Chang Cole, Jacqueline M. Lin, Tze-Chia Sylvester, Sven O. Waddell, Paul G. Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)] |
| author_facet |
Chang, Hui-Chang Cole, Jacqueline M. Lin, Tze-Chia Sylvester, Sven O. Waddell, Paul G. |
| author_sort |
Chang, Hui-Chang |
| title |
Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)] |
| title_short |
Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)] |
| title_full |
Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)] |
| title_fullStr |
Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)] |
| title_full_unstemmed |
Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)] |
| title_sort |
bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(ii)] |
| description |
The asymmetric unit of the title compound, [Cu2(C12H9N2O)2(C7H5O2)2], contains two independent (2-formylphenolato){2-[(pyridin-2-yl)iminomethyl]phenolato}copper(II) molecules that form pseudocentrosymmetric dimers via interactions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17). |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120375/ |
| _version_ |
1611461300129366016 |