Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato}palladium(II)

Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato}palladium(II)

In the title compound, [Pd(C15H13FNO2)2], the PdII atom is tetra­coordinated by two N atoms and two O atoms from the two 2-[(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phen­oxy ligands, forming a square-planar geometry. The two N atoms and the two O atoms around the PdII atom are trans to each other...

Full description

Bibliographic Details
Main Authors: Bahron, Hadariah, Mohd Tajuddin, Amalina, Ibrahim, Wan Nazihah Wan, Hemamalini, Madhukar, Fun, Hoong-Kun
Format: Online
Language:English
Published: International Union of Crystallography 2011
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120330/
id pubmed-3120330
recordtype oai_dc
spelling pubmed-31203302011-07-13 Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato}palladium(II) Bahron, Hadariah Mohd Tajuddin, Amalina Ibrahim, Wan Nazihah Wan Hemamalini, Madhukar Fun, Hoong-Kun Metal-Organic Papers In the title compound, [Pd(C15H13FNO2)2], the PdII atom is tetra­coordinated by two N atoms and two O atoms from the two 2-[(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phen­oxy ligands, forming a square-planar geometry. The two N atoms and the two O atoms around the PdII atom are trans to each other. The dihedral angle between the two fluoro-substituted benzene rings is 39.03 (6)°. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen bond. In the crystal, weak inter­molecular C—H⋯π inter­actions occur. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120330/ /pubmed/21754647 http://dx.doi.org/10.1107/S1600536811017739 Text en © Bahron et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Bahron, Hadariah
Mohd Tajuddin, Amalina
Ibrahim, Wan Nazihah Wan
Hemamalini, Madhukar
Fun, Hoong-Kun
spellingShingle Bahron, Hadariah
Mohd Tajuddin, Amalina
Ibrahim, Wan Nazihah Wan
Hemamalini, Madhukar
Fun, Hoong-Kun
Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato}palladium(II)
author_facet Bahron, Hadariah
Mohd Tajuddin, Amalina
Ibrahim, Wan Nazihah Wan
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Bahron, Hadariah
title Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato}palladium(II)
title_short Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato}palladium(II)
title_full Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato}palladium(II)
title_fullStr Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato}palladium(II)
title_full_unstemmed Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato}palladium(II)
title_sort bis{2-[(e)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato}palladium(ii)
description In the title compound, [Pd(C15H13FNO2)2], the PdII atom is tetra­coordinated by two N atoms and two O atoms from the two 2-[(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phen­oxy ligands, forming a square-planar geometry. The two N atoms and the two O atoms around the PdII atom are trans to each other. The dihedral angle between the two fluoro-substituted benzene rings is 39.03 (6)°. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen bond. In the crystal, weak inter­molecular C—H⋯π inter­actions occur.
publisher International Union of Crystallography
publishDate 2011
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120330/
_version_ 1611461273603538944

Similar Items