(4,5-Diazafluoren-9-one-κ2 N,N′)bis(thiocyanato-κS)mercury(II)
In the title compound, [Hg(NCS)2(C11H6N2O)], the HgII atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetrahedral geometry by an N,N′-bidentate diazafluoren-9-one ligand and two thiocyanate anions. In the crystal, intermolecular C—H⋯N and C—H⋯O hydrogen bonds are effec...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099883/ |
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pubmed-30998832011-07-13 (4,5-Diazafluoren-9-one-κ2 N,N′)bis(thiocyanato-κS)mercury(II) Notash, Behrouz Safari, Nasser Amani, Vahid Metal-Organic Papers In the title compound, [Hg(NCS)2(C11H6N2O)], the HgII atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetrahedral geometry by an N,N′-bidentate diazafluoren-9-one ligand and two thiocyanate anions. In the crystal, intermolecular C—H⋯N and C—H⋯O hydrogen bonds are effective in the stabilization of the structure. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3099883/ /pubmed/21753948 http://dx.doi.org/10.1107/S1600536811008142 Text en © Notash et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Notash, Behrouz Safari, Nasser Amani, Vahid |
| spellingShingle |
Notash, Behrouz Safari, Nasser Amani, Vahid (4,5-Diazafluoren-9-one-κ2 N,N′)bis(thiocyanato-κS)mercury(II) |
| author_facet |
Notash, Behrouz Safari, Nasser Amani, Vahid |
| author_sort |
Notash, Behrouz |
| title |
(4,5-Diazafluoren-9-one-κ2
N,N′)bis(thiocyanato-κS)mercury(II) |
| title_short |
(4,5-Diazafluoren-9-one-κ2
N,N′)bis(thiocyanato-κS)mercury(II) |
| title_full |
(4,5-Diazafluoren-9-one-κ2
N,N′)bis(thiocyanato-κS)mercury(II) |
| title_fullStr |
(4,5-Diazafluoren-9-one-κ2
N,N′)bis(thiocyanato-κS)mercury(II) |
| title_full_unstemmed |
(4,5-Diazafluoren-9-one-κ2
N,N′)bis(thiocyanato-κS)mercury(II) |
| title_sort |
(4,5-diazafluoren-9-one-κ2
n,n′)bis(thiocyanato-κs)mercury(ii) |
| description |
In the title compound, [Hg(NCS)2(C11H6N2O)], the HgII atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetrahedral geometry by an N,N′-bidentate diazafluoren-9-one ligand and two thiocyanate anions. In the crystal, intermolecular C—H⋯N and C—H⋯O hydrogen bonds are effective in the stabilization of the structure. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099883/ |
| _version_ |
1611455172003758080 |