Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ2 N:N′]dimolybdenum(II) tetrahydrofuran solvate
The title complex, [Mo2(C13H9N2Br2)4]·C4H8O, contains a quadruply bonded Mo2 4+ unit equatorially coordinated by four N,N′-bis(4-bromophenyl)formamidinate ligands, forming a dimetal paddlewheel complex. The centroid of the Mo—Mo bond is located on a special position with 2/m symmet...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099865/ |
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pubmed-3099865 |
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pubmed-30998652011-07-13 Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ2 N:N′]dimolybdenum(II) tetrahydrofuran solvate Han, L.-J. Metal-Organic Papers The title complex, [Mo2(C13H9N2Br2)4]·C4H8O, contains a quadruply bonded Mo2 4+ unit equatorially coordinated by four N,N′-bis(4-bromophenyl)formamidinate ligands, forming a dimetal paddlewheel complex. The centroid of the Mo—Mo bond is located on a special position with 2/m symmetry. In the crystal, complex molecules are linked by Br⋯Br interactions [3.7049 (10) Å]. The disordered solvent molecule could not be satisfactorily modelled and was therefore eliminated from the final refinement. International Union of Crystallography 2011-03-31 /pmc/articles/PMC3099865/ /pubmed/21754018 http://dx.doi.org/10.1107/S1600536811011202 Text en © L.-J. Han 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Han, L.-J. |
| spellingShingle |
Han, L.-J. Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ2 N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| author_facet |
Han, L.-J. |
| author_sort |
Han, L.-J. |
| title |
Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ2
N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| title_short |
Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ2
N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| title_full |
Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ2
N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| title_fullStr |
Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ2
N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| title_full_unstemmed |
Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ2
N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| title_sort |
tetrakis[μ-n,n′-bis(4-bromophenyl)formamidinato-κ2
n:n′]dimolybdenum(ii) tetrahydrofuran solvate |
| description |
The title complex, [Mo2(C13H9N2Br2)4]·C4H8O, contains a quadruply bonded Mo2
4+ unit equatorially coordinated by four N,N′-bis(4-bromophenyl)formamidinate ligands, forming a dimetal paddlewheel complex. The centroid of the Mo—Mo bond is located on a special position with 2/m symmetry. In the crystal, complex molecules are linked by Br⋯Br interactions [3.7049 (10) Å]. The disordered solvent molecule could not be satisfactorily modelled and was therefore eliminated from the final refinement. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099865/ |
| _version_ |
1611455159535140864 |