(5-Aminoisophthalato-κN)triaqua(1,10-phenanthroline-κ2 N,N′)nickel(II) trihydrate
The NiII atom in the title compound, [Ni(C8H5NO4)(C12H8N2)(H2O)3]·3H2O, is six-coordinated in an NiN3O3 octahedral geometry. The triply water-coordinated NiII atom is chelated by the phenantroline ligand and is additionally coordinated by the amino group of the 5-aminoisophtalate anion. The anion,...
| Main Authors: | , , |
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| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099854/ |
| Summary: | The NiII atom in the title compound, [Ni(C8H5NO4)(C12H8N2)(H2O)3]·3H2O, is six-coordinated in an NiN3O3 octahedral geometry. The triply water-coordinated NiII atom is chelated by the phenantroline ligand and is additionally coordinated by the amino group of the 5-aminoisophtalate anion. The anion, the coordinated and the uncoordinated water molecules interact through an extensive O—H⋯O and N—H⋯O hydrogen-bonding network, generating a three-dimensional cage-like network. |
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