catena-Poly[[octaaquabis(μ4-benzene-1,3,5-tricarboxylato)trizinc] tetrahydrate]
In the title compound, {[Zn3(C9H3O6)2(H2O)8]·4H2O}n, there are two crystallographically independent ZnII ions. One presents a trigonal-bipyramidal coordination geometry defined by five O atoms [three from two carboxylate groups of two benzene-1,3,5-tricarboxylate (BTC) ligands and the other two de...
| Main Authors: | , , |
|---|---|
| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2011
|
| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089220/ |
| id |
pubmed-3089220 |
|---|---|
| recordtype |
oai_dc |
| spelling |
pubmed-30892202011-07-13 catena-Poly[[octaaquabis(μ4-benzene-1,3,5-tricarboxylato)trizinc] tetrahydrate] Sun, Lin Qiu, Tao Run Deng, Hong Metal-Organic Papers In the title compound, {[Zn3(C9H3O6)2(H2O)8]·4H2O}n, there are two crystallographically independent ZnII ions. One presents a trigonal-bipyramidal coordination geometry defined by five O atoms [three from two carboxylate groups of two benzene-1,3,5-tricarboxylate (BTC) ligands and the other two deriving from three water molecules], while the other lies on an inversion centre and exists in a slightly distorted octahedral coordination geometry defined by six O atoms (two from two carboxylate groups of two BTC ligands and the others from four water molecules). A three-dimensional framework is further strengthened via O—H⋯O hydrogen-bonding interactons. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089220/ /pubmed/21754339 http://dx.doi.org/10.1107/S160053681101436X Text en © Sun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Sun, Lin Qiu, Tao Run Deng, Hong |
| spellingShingle |
Sun, Lin Qiu, Tao Run Deng, Hong catena-Poly[[octaaquabis(μ4-benzene-1,3,5-tricarboxylato)trizinc] tetrahydrate] |
| author_facet |
Sun, Lin Qiu, Tao Run Deng, Hong |
| author_sort |
Sun, Lin |
| title |
catena-Poly[[octaaquabis(μ4-benzene-1,3,5-tricarboxylato)trizinc] tetrahydrate] |
| title_short |
catena-Poly[[octaaquabis(μ4-benzene-1,3,5-tricarboxylato)trizinc] tetrahydrate] |
| title_full |
catena-Poly[[octaaquabis(μ4-benzene-1,3,5-tricarboxylato)trizinc] tetrahydrate] |
| title_fullStr |
catena-Poly[[octaaquabis(μ4-benzene-1,3,5-tricarboxylato)trizinc] tetrahydrate] |
| title_full_unstemmed |
catena-Poly[[octaaquabis(μ4-benzene-1,3,5-tricarboxylato)trizinc] tetrahydrate] |
| title_sort |
catena-poly[[octaaquabis(μ4-benzene-1,3,5-tricarboxylato)trizinc] tetrahydrate] |
| description |
In the title compound, {[Zn3(C9H3O6)2(H2O)8]·4H2O}n, there are two crystallographically independent ZnII ions. One presents a trigonal-bipyramidal coordination geometry defined by five O atoms [three from two carboxylate groups of two benzene-1,3,5-tricarboxylate (BTC) ligands and the other two deriving from three water molecules], while the other lies on an inversion centre and exists in a slightly distorted octahedral coordination geometry defined by six O atoms (two from two carboxylate groups of two BTC ligands and the others from four water molecules). A three-dimensional framework is further strengthened via O—H⋯O hydrogen-bonding interactons. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089220/ |
| _version_ |
1611452342138306560 |