2,2-Dimethyl-5-[(2-nitroanilino)methylidene]-1,3-dioxane-4,6-dione
The crystal of the title compound, C13H12N2O6, contains a bifurcated intramolecular hydrogen bond between the N—H group and one of the O atoms from both the nitro group and the dioxane-4,6-dione moiety. In addition, molecules are linked by a series of intermolecular C—H⋯O secondary interactions....
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089138/ |
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pubmed-3089138 |
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oai_dc |
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pubmed-30891382011-07-13 2,2-Dimethyl-5-[(2-nitroanilino)methylidene]-1,3-dioxane-4,6-dione He, Yu-xin Wu, Jin-wei Tong, Rong-sheng Shi, Jian-you Organic Papers The crystal of the title compound, C13H12N2O6, contains a bifurcated intramolecular hydrogen bond between the N—H group and one of the O atoms from both the nitro group and the dioxane-4,6-dione moiety. In addition, molecules are linked by a series of intermolecular C—H⋯O secondary interactions. The dihedral angles between the benzene ring and the nitro group and the conjugated part of the dioxane-4,6-dione moiety are 19.1 (2) and 17.89 (7)°, respectively. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089138/ /pubmed/21754514 http://dx.doi.org/10.1107/S1600536811014358 Text en © He et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
He, Yu-xin Wu, Jin-wei Tong, Rong-sheng Shi, Jian-you |
| spellingShingle |
He, Yu-xin Wu, Jin-wei Tong, Rong-sheng Shi, Jian-you 2,2-Dimethyl-5-[(2-nitroanilino)methylidene]-1,3-dioxane-4,6-dione |
| author_facet |
He, Yu-xin Wu, Jin-wei Tong, Rong-sheng Shi, Jian-you |
| author_sort |
He, Yu-xin |
| title |
2,2-Dimethyl-5-[(2-nitroanilino)methylidene]-1,3-dioxane-4,6-dione |
| title_short |
2,2-Dimethyl-5-[(2-nitroanilino)methylidene]-1,3-dioxane-4,6-dione |
| title_full |
2,2-Dimethyl-5-[(2-nitroanilino)methylidene]-1,3-dioxane-4,6-dione |
| title_fullStr |
2,2-Dimethyl-5-[(2-nitroanilino)methylidene]-1,3-dioxane-4,6-dione |
| title_full_unstemmed |
2,2-Dimethyl-5-[(2-nitroanilino)methylidene]-1,3-dioxane-4,6-dione |
| title_sort |
2,2-dimethyl-5-[(2-nitroanilino)methylidene]-1,3-dioxane-4,6-dione |
| description |
The crystal of the title compound, C13H12N2O6, contains a bifurcated intramolecular hydrogen bond between the N—H group and one of the O atoms from both the nitro group and the dioxane-4,6-dione moiety. In addition, molecules are linked by a series of intermolecular C—H⋯O secondary interactions. The dihedral angles between the benzene ring and the nitro group and the conjugated part of the dioxane-4,6-dione moiety are 19.1 (2) and 17.89 (7)°, respectively. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089138/ |
| _version_ |
1611452294051659776 |