Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate
The tetranuclear title complex, [Cu4(C7H4O3)2(OH)2(C10H8N2)4](NO3)2·4H2O, has a crystallographically imposed centre of symmetry. The CuII atoms display a distorted square-pyramidal coordination geometry and are linked by two μ2-phenolate O atoms from the salicylate ligands and two μ3-hydroxo groups...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089088/ |
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pubmed-30890882011-07-13 Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate Feng, Miao Gu, Chao Mi, Huai-Feng Hu, Tong-Liang Metal-Organic Papers The tetranuclear title complex, [Cu4(C7H4O3)2(OH)2(C10H8N2)4](NO3)2·4H2O, has a crystallographically imposed centre of symmetry. The CuII atoms display a distorted square-pyramidal coordination geometry and are linked by two μ2-phenolate O atoms from the salicylate ligands and two μ3-hydroxo groups, forming a Cu4O4 core that adopts a ‘stepped-cubane’ geometry. In the crystal, the cations are linked by O—H⋯O hydrogen bonds to the nitrate anions, which are in turn connected via O—H⋯O interactions to centrosymmentric water tetramers. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089088/ /pubmed/21754263 http://dx.doi.org/10.1107/S1600536811011433 Text en © Feng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Feng, Miao Gu, Chao Mi, Huai-Feng Hu, Tong-Liang |
| spellingShingle |
Feng, Miao Gu, Chao Mi, Huai-Feng Hu, Tong-Liang Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate |
| author_facet |
Feng, Miao Gu, Chao Mi, Huai-Feng Hu, Tong-Liang |
| author_sort |
Feng, Miao |
| title |
Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate |
| title_short |
Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate |
| title_full |
Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate |
| title_fullStr |
Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate |
| title_full_unstemmed |
Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate |
| title_sort |
tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(ii) dinitrate tetrahydrate |
| description |
The tetranuclear title complex, [Cu4(C7H4O3)2(OH)2(C10H8N2)4](NO3)2·4H2O, has a crystallographically imposed centre of symmetry. The CuII atoms display a distorted square-pyramidal coordination geometry and are linked by two μ2-phenolate O atoms from the salicylate ligands and two μ3-hydroxo groups, forming a Cu4O4 core that adopts a ‘stepped-cubane’ geometry. In the crystal, the cations are linked by O—H⋯O hydrogen bonds to the nitrate anions, which are in turn connected via O—H⋯O interactions to centrosymmentric water tetramers. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089088/ |
| _version_ |
1611452261070798848 |