cis-Di-μ-oxido-bis[(N,N-diethyldithiocarbamato-κ2 S,S′)oxidomolybdenum(V)](Mo—Mo) tetrahydrofuran monosolvate
The title compound, [Mo2(C5H10NS2)2O4]·C4H8O, can be readily prepared in tetrahydrofuran (THF) by an oxidation reaction between the MoIV precursor [MoO(S2CNEt2)2] with [ReMeO3]. The compound is an axially symmetric MoV dimer (2 symmetry), in which the metal atoms exhibit a distorted square-pyramid...
| Main Authors: | , , |
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| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051765/ |