Adeninium perchlorate
In the title salt (systematic name: 6-amino-9H-purin-1-ium perchlorate), C5H6N5 +·ClO4 −, the adeninium cation is essentially planar, with a maximum deviation of 0.038 (1) Å. The whole of the perchlorate anion is disordered over two sets of sites with an occupancy ratio...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051488/ |
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pubmed-30514882011-04-26 Adeninium perchlorate Fun, Hoong-Kun Goh, Jia Hao Maity, Annada C. Goswami, Shyamaprosad Organic Papers In the title salt (systematic name: 6-amino-9H-purin-1-ium perchlorate), C5H6N5 +·ClO4 −, the adeninium cation is essentially planar, with a maximum deviation of 0.038 (1) Å. The whole of the perchlorate anion is disordered over two sets of sites with an occupancy ratio of 0.589 (13):0.411 (13). In the crystal, the adeninium cations are linked by pairs of N—H⋯N hydrogen bond into inversion dimers. The dimers and the anions are further interconnected into a three-dimensional supramolecular structure via intermolecular N—H⋯O, C—H⋯O and C—H⋯N hydrogen bonds. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051488/ /pubmed/21523095 http://dx.doi.org/10.1107/S1600536811001528 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Fun, Hoong-Kun Goh, Jia Hao Maity, Annada C. Goswami, Shyamaprosad |
| spellingShingle |
Fun, Hoong-Kun Goh, Jia Hao Maity, Annada C. Goswami, Shyamaprosad Adeninium perchlorate |
| author_facet |
Fun, Hoong-Kun Goh, Jia Hao Maity, Annada C. Goswami, Shyamaprosad |
| author_sort |
Fun, Hoong-Kun |
| title |
Adeninium perchlorate |
| title_short |
Adeninium perchlorate |
| title_full |
Adeninium perchlorate |
| title_fullStr |
Adeninium perchlorate |
| title_full_unstemmed |
Adeninium perchlorate |
| title_sort |
adeninium perchlorate |
| description |
In the title salt (systematic name: 6-amino-9H-purin-1-ium perchlorate), C5H6N5
+·ClO4
−, the adeninium cation is essentially planar, with a maximum deviation of 0.038 (1) Å. The whole of the perchlorate anion is disordered over two sets of sites with an occupancy ratio of 0.589 (13):0.411 (13). In the crystal, the adeninium cations are linked by pairs of N—H⋯N hydrogen bond into inversion dimers. The dimers and the anions are further interconnected into a three-dimensional supramolecular structure via intermolecular N—H⋯O, C—H⋯O and C—H⋯N hydrogen bonds. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051488/ |
| _version_ |
1611443612196798464 |