Bis[1,3-bis(2,4,6-trimethylphenyl)-2,3-dihydro-1H-imidazol-2-ylidene]dichloridodinitrosyltungsten(II) tetrahydrofuran-d 8 monosolvate
The molecular structure of the title compound, [WCl2(NO)2(C21H24N2)2]·C4D8O, displays a distorted octahedral arrangement around the W atom with two trans 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) carbene ligands in axial positions. The four equatorial positions are occupied by ni...
| Main Authors: | , , |
|---|---|
| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2010
|
| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050297/ |
| id |
pubmed-3050297 |
|---|---|
| recordtype |
oai_dc |
| spelling |
pubmed-30502972011-04-26 Bis[1,3-bis(2,4,6-trimethylphenyl)-2,3-dihydro-1H-imidazol-2-ylidene]dichloridodinitrosyltungsten(II) tetrahydrofuran-d 8 monosolvate Fraga-Hernández, Javier Blacque, Olivier Berke, Heinz Metal-Organic Papers The molecular structure of the title compound, [WCl2(NO)2(C21H24N2)2]·C4D8O, displays a distorted octahedral arrangement around the W atom with two trans 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) carbene ligands in axial positions. The four equatorial positions are occupied by nitrosyl and chloride ligands, which are trans to each other. The Ccarbene—W—Ccarbene bond angle of 173.44 (18)° and the Cl—W—Nnitrosyl bond angles of 171.34 (11) and 171.32 (13)° deviate only slightly from linearity. The distortion comes from the nitrosyl and chloride ligands which are not fully coplanar since the two N atoms deviate from the WCl2 plane by −0.279 (4) and 0.272 (4) Å, respectively. An intermolecular C—H⋯O interaction connects the organometallic molecule and the tetrahydrofuran-d 8 solvent molecule. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050297/ /pubmed/21522555 http://dx.doi.org/10.1107/S1600536810050099 Text en © Fraga-Hernández et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Fraga-Hernández, Javier Blacque, Olivier Berke, Heinz |
| spellingShingle |
Fraga-Hernández, Javier Blacque, Olivier Berke, Heinz Bis[1,3-bis(2,4,6-trimethylphenyl)-2,3-dihydro-1H-imidazol-2-ylidene]dichloridodinitrosyltungsten(II) tetrahydrofuran-d 8 monosolvate |
| author_facet |
Fraga-Hernández, Javier Blacque, Olivier Berke, Heinz |
| author_sort |
Fraga-Hernández, Javier |
| title |
Bis[1,3-bis(2,4,6-trimethylphenyl)-2,3-dihydro-1H-imidazol-2-ylidene]dichloridodinitrosyltungsten(II) tetrahydrofuran-d
8 monosolvate |
| title_short |
Bis[1,3-bis(2,4,6-trimethylphenyl)-2,3-dihydro-1H-imidazol-2-ylidene]dichloridodinitrosyltungsten(II) tetrahydrofuran-d
8 monosolvate |
| title_full |
Bis[1,3-bis(2,4,6-trimethylphenyl)-2,3-dihydro-1H-imidazol-2-ylidene]dichloridodinitrosyltungsten(II) tetrahydrofuran-d
8 monosolvate |
| title_fullStr |
Bis[1,3-bis(2,4,6-trimethylphenyl)-2,3-dihydro-1H-imidazol-2-ylidene]dichloridodinitrosyltungsten(II) tetrahydrofuran-d
8 monosolvate |
| title_full_unstemmed |
Bis[1,3-bis(2,4,6-trimethylphenyl)-2,3-dihydro-1H-imidazol-2-ylidene]dichloridodinitrosyltungsten(II) tetrahydrofuran-d
8 monosolvate |
| title_sort |
bis[1,3-bis(2,4,6-trimethylphenyl)-2,3-dihydro-1h-imidazol-2-ylidene]dichloridodinitrosyltungsten(ii) tetrahydrofuran-d
8 monosolvate |
| description |
The molecular structure of the title compound, [WCl2(NO)2(C21H24N2)2]·C4D8O, displays a distorted octahedral arrangement around the W atom with two trans 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) carbene ligands in axial positions. The four equatorial positions are occupied by nitrosyl and chloride ligands, which are trans to each other. The Ccarbene—W—Ccarbene bond angle of 173.44 (18)° and the Cl—W—Nnitrosyl bond angles of 171.34 (11) and 171.32 (13)° deviate only slightly from linearity. The distortion comes from the nitrosyl and chloride ligands which are not fully coplanar since the two N atoms deviate from the WCl2 plane by −0.279 (4) and 0.272 (4) Å, respectively. An intermolecular C—H⋯O interaction connects the organometallic molecule and the tetrahydrofuran-d
8 solvent molecule. |
| publisher |
International Union of Crystallography |
| publishDate |
2010 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050297/ |
| _version_ |
1611443220747649024 |