The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
Across the periodic table the trans-influence operates, whereby tightly bonded ligands selectively lengthen mutually trans metal–ligand bonds. Conversely, in high oxidation state actinide complexes the inverse-trans-influence operates, where normally cis strongly donating ligands instead reside tran...
| Main Authors: | , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Publishing Group
2017
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| Online Access: | http://eprints.nottingham.ac.uk/41181/ http://eprints.nottingham.ac.uk/41181/ http://eprints.nottingham.ac.uk/41181/ http://eprints.nottingham.ac.uk/41181/1/ncomms14137.pdf |