Amides do not always work: observation of guest binding in an amide-functionalised porous host

Amides do not always work: observation of guest binding in an amide-functionalised porous host

An amide-functionalised metal organic frame-work (MOF) material, MFM-136, shows a high CO2 uptake of 12.6 mmol g-1 at 20 bar and 298 K. MFM-136 is the first example of acylamide pyrimidyl isophthalate MOF without open metal sites, and thus provides a unique platform to study guest bind-ing, particul...

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Bibliographic Details
Main Authors: Benson, Oguarabau, Da Silva, Ivan, Argent, Stephen P., Cabot, Rafel, Savage, Mathew, Godfrey, Harry G.W., Yan, Yong, Parker, Stewart F., Manuel, Pascal, Lennox, Matthew J., Mitra, Tamoghna, Easun, Timothy L., Lewis, William, Blake, Alexander J., Besley, Elena, Yang, Sihai, Schröder, Martin
Format: Article
Language:English
Published: American Chemical Society 2016
Online Access:http://eprints.nottingham.ac.uk/38948/
http://eprints.nottingham.ac.uk/38948/
http://eprints.nottingham.ac.uk/38948/
http://eprints.nottingham.ac.uk/38948/1/%28Submitted%29%20Amides%20Do%20Not%20Always%20Work%20-%20Observation%20of%20Guest%20Binding%20in%20an%20Amide-Functionalized%20Porous%20MOF.pdf

Internet

http://eprints.nottingham.ac.uk/38948/
http://eprints.nottingham.ac.uk/38948/
http://eprints.nottingham.ac.uk/38948/
http://eprints.nottingham.ac.uk/38948/1/%28Submitted%29%20Amides%20Do%20Not%20Always%20Work%20-%20Observation%20of%20Guest%20Binding%20in%20an%20Amide-Functionalized%20Porous%20MOF.pdf

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