Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation
We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature. The regiospecific reaction invovles the coupling of phosphines with aryl radicals derived from diaryliodonium salts under photoredox conditions.
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2016
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| Online Access: | http://eprints.nottingham.ac.uk/32151/ http://eprints.nottingham.ac.uk/32151/ http://eprints.nottingham.ac.uk/32151/ http://eprints.nottingham.ac.uk/32151/1/Phosphonium%20paper%20for%20deposition.pdf |