Vibrations of the S1 state of fluorobenzene-h5 and fluorobenzene-d5 via resonance-enhanced multiphoton ionization (REMPI) spectroscopy

We report resonance-enhanced multiphoton ionization spectra of the isotopologues fluorobenzeneh5 and fluorobenzene-d5. By making use of quantum chemical calculations, the changes in the wavenumber of the vibrational modes upon deuteration are examined. Additionally, the mixing of vibrational modes b...

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Main Authors:	Harris, Joe P., Andrejeva, Anna, Tuttle, William D., Pugliesi, Igor, Schriever, Christian, Wright, Timothy G.
Format:	Article
Language:	English
Published:	American Institute of Physics 2014
Online Access:	http://eprints.nottingham.ac.uk/28799/ http://eprints.nottingham.ac.uk/28799/ http://eprints.nottingham.ac.uk/28799/ http://eprints.nottingham.ac.uk/28799/1/Published%20Article.pdf

id	nottingham-28799
recordtype	eprints
spelling	nottingham-287992017-10-12T19:11:27Z http://eprints.nottingham.ac.uk/28799/ Vibrations of the S1 state of fluorobenzene-h5 and fluorobenzene-d5 via resonance-enhanced multiphoton ionization (REMPI) spectroscopy Harris, Joe P. Andrejeva, Anna Tuttle, William D. Pugliesi, Igor Schriever, Christian Wright, Timothy G. We report resonance-enhanced multiphoton ionization spectra of the isotopologues fluorobenzeneh5 and fluorobenzene-d5. By making use of quantum chemical calculations, the changes in the wavenumber of the vibrational modes upon deuteration are examined. Additionally, the mixing of vibrational modes both between isotopologues and also between the two electronic states is discussed. The isotopic shifts lead to dramatic changes in the appearance of the spectrum as vibrations shift in and out of Fermi resonance. Assignments of the majority of the fluorobenzene-d5 observed bands are provided, aided by previous results on fluorobenzene-h5. American Institute of Physics 2014-12-31 Article PeerReviewed application/pdf en http://eprints.nottingham.ac.uk/28799/1/Published%20Article.pdf Harris, Joe P. and Andrejeva, Anna and Tuttle, William D. and Pugliesi, Igor and Schriever, Christian and Wright, Timothy G. (2014) Vibrations of the S1 state of fluorobenzene-h5 and fluorobenzene-d5 via resonance-enhanced multiphoton ionization (REMPI) spectroscopy. Journal of Chemical Physics, 141 (24). 244315/1-244315/15. ISSN 0021-9606 http://scitation.aip.org/content/aip/journal/jcp/141/24/10.1063/1.4904706 doi:10.1063/1.4904706 doi:10.1063/1.4904706
repository_type	Digital Repository
institution_category	Local University
institution	University of Nottingham Malaysia Campus
building	Nottingham Research Data Repository
collection	Online Access
language	English
description	We report resonance-enhanced multiphoton ionization spectra of the isotopologues fluorobenzeneh5 and fluorobenzene-d5. By making use of quantum chemical calculations, the changes in the wavenumber of the vibrational modes upon deuteration are examined. Additionally, the mixing of vibrational modes both between isotopologues and also between the two electronic states is discussed. The isotopic shifts lead to dramatic changes in the appearance of the spectrum as vibrations shift in and out of Fermi resonance. Assignments of the majority of the fluorobenzene-d5 observed bands are provided, aided by previous results on fluorobenzene-h5.
format	Article
author	Harris, Joe P. Andrejeva, Anna Tuttle, William D. Pugliesi, Igor Schriever, Christian Wright, Timothy G.
spellingShingle	Harris, Joe P. Andrejeva, Anna Tuttle, William D. Pugliesi, Igor Schriever, Christian Wright, Timothy G. Vibrations of the S1 state of fluorobenzene-h5 and fluorobenzene-d5 via resonance-enhanced multiphoton ionization (REMPI) spectroscopy
author_facet	Harris, Joe P. Andrejeva, Anna Tuttle, William D. Pugliesi, Igor Schriever, Christian Wright, Timothy G.
author_sort	Harris, Joe P.
title	Vibrations of the S1 state of fluorobenzene-h5 and fluorobenzene-d5 via resonance-enhanced multiphoton ionization (REMPI) spectroscopy
title_short	Vibrations of the S1 state of fluorobenzene-h5 and fluorobenzene-d5 via resonance-enhanced multiphoton ionization (REMPI) spectroscopy
title_full	Vibrations of the S1 state of fluorobenzene-h5 and fluorobenzene-d5 via resonance-enhanced multiphoton ionization (REMPI) spectroscopy
title_fullStr	Vibrations of the S1 state of fluorobenzene-h5 and fluorobenzene-d5 via resonance-enhanced multiphoton ionization (REMPI) spectroscopy
title_full_unstemmed	Vibrations of the S1 state of fluorobenzene-h5 and fluorobenzene-d5 via resonance-enhanced multiphoton ionization (REMPI) spectroscopy
title_sort	vibrations of the s1 state of fluorobenzene-h5 and fluorobenzene-d5 via resonance-enhanced multiphoton ionization (rempi) spectroscopy
publisher	American Institute of Physics
publishDate	2014
url	http://eprints.nottingham.ac.uk/28799/ http://eprints.nottingham.ac.uk/28799/ http://eprints.nottingham.ac.uk/28799/ http://eprints.nottingham.ac.uk/28799/1/Published%20Article.pdf
first_indexed	2018-09-06T11:51:46Z
last_indexed	2018-09-06T11:51:46Z
_version_	1610858843856699392

Vibrations of the S1 state of fluorobenzene-h5 and fluorobenzene-d5 via resonance-enhanced multiphoton ionization (REMPI) spectroscopy

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