The Importance of Solvent Effects on the Mechanism of the Pfeiffer Effect

The Importance of Solvent Effects on the Mechanism of the Pfeiffer Effect

The Pfeiffer effect is observed when an optically active compound such as an amino acid is introduced to a solution containing a labile racemic metal complex, and an equilibrium shift is obtained. The “perturbation” results in an excess of one enantiomer over the other. The shift...

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Bibliographic Details
Main Authors: Jamie L. Lunkley, Ngoc M. Nguyen, Kristina M. Tuminaro, Dana Margittai, Gilles Muller
Format: Article
Language:English
Published: MDPI AG 2018-08-01
Series:Inorganics
Subjects:
circularly polarized luminescence
chirality transfer
hydrophobic interactions
D3 lanthanide(III) complexes
chiral amino acid
solvent packing
Online Access:http://www.mdpi.com/2304-6740/6/3/87

Internet

http://www.mdpi.com/2304-6740/6/3/87

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