Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine

The enantioselectivity of the autocatalytic alkylation of 2-tert-butylpyrimidyl-5-carbaldehyde, initiated by chiral crystals of N-(2-thienylcarbonyl)glycine, is predicted computationally. The results are in accord with the correlation of the stereochemical outcome of the reaction and the absolute st...

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Main Authors:	Carter, Damien, Rohl, Andrew, Shtukenberg, A., Bian, S., Hu, C., Baylon, L., Kahr, B., Mineki, H., Abe, K., Kawasaki, T., Soai, K.
Format:	Journal Article
Published:	American Chemical Society 2012
Online Access:	http://pubs.acs.org/doi/abs/10.1021/cg300207d http://hdl.handle.net/20.500.11937/9789

id	curtin-20.500.11937-9789
recordtype	eprints
spelling	curtin-20.500.11937-97892018-08-08T04:54:56Z Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine Carter, Damien Rohl, Andrew Shtukenberg, A. Bian, S. Hu, C. Baylon, L. Kahr, B. Mineki, H. Abe, K. Kawasaki, T. Soai, K. The enantioselectivity of the autocatalytic alkylation of 2-tert-butylpyrimidyl-5-carbaldehyde, initiated by chiral crystals of N-(2-thienylcarbonyl)glycine, is predicted computationally. The results are in accord with the correlation of the stereochemical outcome of the reaction and the absolute structure of the crystals determined by the anomalous dispersion of X-rays and circular dichroism spectroscopy. 2012 Journal Article http://hdl.handle.net/20.500.11937/9789 http://pubs.acs.org/doi/abs/10.1021/cg300207d American Chemical Society restricted
repository_type	Digital Repository
institution_category	Local University
institution	Curtin University Malaysia
building	Curtin Institutional Repository
collection	Online Access
description	The enantioselectivity of the autocatalytic alkylation of 2-tert-butylpyrimidyl-5-carbaldehyde, initiated by chiral crystals of N-(2-thienylcarbonyl)glycine, is predicted computationally. The results are in accord with the correlation of the stereochemical outcome of the reaction and the absolute structure of the crystals determined by the anomalous dispersion of X-rays and circular dichroism spectroscopy.
format	Journal Article
author	Carter, Damien Rohl, Andrew Shtukenberg, A. Bian, S. Hu, C. Baylon, L. Kahr, B. Mineki, H. Abe, K. Kawasaki, T. Soai, K.
spellingShingle	Carter, Damien Rohl, Andrew Shtukenberg, A. Bian, S. Hu, C. Baylon, L. Kahr, B. Mineki, H. Abe, K. Kawasaki, T. Soai, K. Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine
author_facet	Carter, Damien Rohl, Andrew Shtukenberg, A. Bian, S. Hu, C. Baylon, L. Kahr, B. Mineki, H. Abe, K. Kawasaki, T. Soai, K.
author_sort	Carter, Damien
title	Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine
title_short	Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine
title_full	Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine
title_fullStr	Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine
title_full_unstemmed	Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine
title_sort	prediction of soai reaction enantioselectivity induced by crystals of n-(2-thienylcarbonyl)glycine
publisher	American Chemical Society
publishDate	2012
url	http://pubs.acs.org/doi/abs/10.1021/cg300207d http://hdl.handle.net/20.500.11937/9789
first_indexed	2018-09-06T18:37:42Z
last_indexed	2018-09-06T18:37:42Z
_version_	1610884382982144000

Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine

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