Ru-based olefin metathesis catalysts bearing ph-responsive n-heterocyclic carbene (NHC) ligands: Activity control via degree of protonation

Olefin metathesis catalysts (H2ITap)(PCy3)Cl2Ru=CHPh (4)and (H2ITap)Cl2Ru=CH-(C6H4-O-iPr) (5)[H2ITap = 1,3-bis-(2-,6-dimethyl-4- dimethylaminophenyl)-4,5-dihydroimid-azol-2-ylidene] were used for the ring-opening metathesispolymerization (ROMP) of exo-7-oxanorbornene derivative 7in the presence of v...

Full description

Bibliographic Details
Main Authors: Balof, S., Yu, B., Lowe, Andrew, Ling, Y., Zhang, Y., Schanz, H.
Format: Journal Article
Published: Wiley - V C H Verlag GmbH 2009
Online Access:http://hdl.handle.net/20.500.11937/5682