Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths

© 2015 The Royal Society of Chemistry. For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T-deuterium bond length (T = Fe, Co, Ni) and the average electronegativity of the metal countercations. This relationship can be further employed towards...

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Bibliographic Details
Main Authors: Humphries, Terry, Sheppard, Drew, Buckley, Craig
Format: Journal Article
Published: Royal Society of Chemistry 2015
Online Access:http://hdl.handle.net/20.500.11937/4697