Synthesis, thiol-yne "click" photopolymerization, and physical properties of networks derived from novel multifunctional alkynes
Multifunctional alkynes (2, 3, or 4 ynes per monomer) were prepared utilizing the nucleophile-catalyzed thio-Michael addition reaction from commercially available multifunctional thiols (2, 3, or 4 thiols) and propargyl acrylate. Real-time FTIR (RTIR) and NMR spectroscopies indicate that the conjuga...
| Main Authors: | , , , , |
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| Format: | Journal Article |
| Published: |
American Chemical Society
2010
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| Online Access: | http://hdl.handle.net/20.500.11937/46502 |