Structure and decomposition of zinc borohydride ammonia adduct: towards a pure hydrogen release
Zn(BH4)2.2NH3, a new ammine metal borohydride, has been synthesized via simply ball-milling a mixture of ZnCl2.2NH3/2LiBH4. Structure analysis shows that the subsequent complex has a monoclinic structure with unit-cell parameters of a = 6.392(4) A, b = 8.417(6) A, c = 6.388(4) A and β = 92.407(4)° a...
| Main Authors: | , , , , , , , |
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| Format: | Journal Article |
| Published: |
Royal Society of Chemistry
2012
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| Online Access: | http://hdl.handle.net/20.500.11937/43259 |