A Combined Computational–Experimental Study of the Kinetics of Intramolecular Diels–AlderReactions in a Series of 1,3,8-Nonatrienes

A Combined Computational–Experimental Study of the Kinetics of Intramolecular Diels–AlderReactions in a Series of 1,3,8-Nonatrienes

Activation enthalpies for a series of five 1,3,8-nonatriene intramolecular Diels–Alder (IMDA) reactions involving substrates 1–5 have been determined experimentally and Singleton’s natural abundance method has been employed to determine kinetic isotope effects in the IMDA reaction of fumarate 3. The...

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Bibliographic Details
Main Authors: Lording, W., Payne, Alan, Cayzer, T., Sherburn, M., Paddon-Row, M.
Format: Journal Article
Published: CSIRO Publishing 2014
Subjects:
3
8-nonatriene intramolecular Diels–Alder (IMDA) and activation enthalpies
1
Kinetic isotope
Online Access:http://hdl.handle.net/20.500.11937/28005

Internet

http://hdl.handle.net/20.500.11937/28005

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