Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV)
The dimethylsulfoxide (dmso) solvate of Th(IV) perchlorate is readily obtained from acidic aqueous Th(IV) solutions and has a formulation established from a single crystal structure determination of [Th(dmso-O)9](ClO4)4 . 4dmso; triclinic, P1, a = 12:4811(8)A, b = 12:4879(8)A, c = 23:969(2)A, a = 94...
| Main Authors: | , , , |
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| Format: | Journal Article |
| Published: |
Elsevier
2004
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| Subjects: | |
| Online Access: | http://hdl.handle.net/20.500.11937/18415 |