Deprotonation of large calixarenes-cation binding and conformations

© 2016 CSIRO. Single crystal X-ray studies of p-t-butylcalix[10]arene·2dmso·7H2O (1) and [NMe4][p-t-butylcalix[9]arene-H]·2dmso·H2O (2), provide new data on these large macrocycles and their conformations, that of 2 being the first where an encapsulated [NMe4]+ cation is present, while 1 contains th...

Full description

Bibliographic Details
Main Authors: Harrowfield, J., Koutsantonis, G., Ogden, Mark, Sobolev, A., White, A.
Format: Journal Article
Published: CSIRO Publishing 2016
Online Access:http://hdl.handle.net/20.500.11937/18274