Search Results - "ring system"
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Synthesis of [5:5] pyrazolidinone and [5:7] oxazepanone γ-Lactam ring systems / Fatin Nur Ain Abdul Rashid
Published 2020“…The second part focused on the formation of 3,4-fused [5:5] pyrazolidinone γ-lactam bicyclic ring system. The key intermediate; 2,3-dioxopyrrolidine underwent nucleophilic addition reaction at C-3 position via insertion of hydrazine hydrate by refluxing in ethanol solvent. …”
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Ethyl 1-sec-butyl-2-phenyl-1H-benzimidazole-5-carboxylate
Published 2010“…In the title molecule, C20H22N2O2, the benzimidazole ring system is essentially planar, with a maximum deviation of 0.024 (1) A ˚ . …”
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Adventures in natural product chemistry
Published 2020“…Halichlorine, pinnaic acid and pinnarine are a novel family of marine alkaloids, characterised by their common 6-aza-spiro[4.5]decane ring system. First isolated in 1996 by Uemura et al, they have been shown to be biologically active with potential applications in the fields of inflammatory response and tumor metastasis. …”
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Ethyl 1-(2-hydroxyethyl)-2-phenyl-1H-benzimidazole-5-carboxylate
Published 2010“…In each one, the benzimidazole ring system is essentially planar, with maximum deviations of There are two molecules in the asymmetric unit of the title compound, C18H18N2O3. …”
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The atomization current and droplet size of ethanol in two different small-scale electro-spraying systems
Published 2017“…Both of the nozzle and the nozzle-ring systems show a good agreement with Rayleigh instability.…”
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Studies towards the synthesis of 4-hydroxybenzyl 3-acyltetramic acid / Norhanim Mohalid
Published 2016“…The tetramic acid (pyrrolidine-2,4-dione) ring system is present as a key structural unit in many natural products. …”
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Synthesis, Characterisation And Cytotoxicity Study Of Some New 1,2,4-Triazole Derivatives
Published 2017“…Dalam kajian ini, 36 sebatian baru 1,2,4-triazol dengan sistem gelang mono dan terlakur telah disintesis dan dicirikan In this study, 36 new 1,2,4-triazole compounds with mono and fused ring system have been synthesised and characterised …”
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Isolation, structure elucidation and cytotoxic activity of cucurbitacins from Elaeocarpus petiolatus
Published 2019“…Compound 1 represents a rare cucurbitacin incorporating an unusual furan-bearing side chain with ketal and epoxide functions, while compound 2 possesses a rare six-fused ring system incorporating a pyranofuranyl ring system. …”
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On the influence of small chemical changes upon the supramolecular association in substituted 2-(phenoxy)-1,4-naphthoquinones
Published 2019“…X-ray crystallography reveals the common feature of the title compounds is a 1,4-naphthoquinone ring system with a substituted phenoxy residue adjacent to an oxo-group to give 1 (H), 2 (3-Br), 3 (3-CF3), 4 (4-CN) and 5 (4-NO2). …”
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Synthesis of spirocyclic enones by rhodium-catalyzed dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes
Published 2014“…These reactions are successful using Cu(OAc)2 or air as the stoichiometric oxidant, and provide spirocyclic enones, the basic ring system of which appears in several natural products. …”
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Catalytic performance of chars as catalyst for reforming pyrolytic tars from Shengli lignite pyrolysis
Published 2013“…In the presence of catalysts (especially the activated char), the tar production dropped while the propor tion of large aromatic ring system in tar also significantly changed. The tar yields were generally decreasing with increasing reaction temperatures from 700 to 900 °C, but the increase in temperature changed the tar chemical compositions differently between slow and fast heating rates.…”
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2-Quinolylmethyl N0-[1-(m-tolyl) ethylidene] hydrazinecarbodithioate
Published 2007“…The title compound, C20H19N3S2, crystallized as a cis–trans conformer in which the quinoline ring system is cis across the C—S bond but adopts a trans geometry with respect to the C—N bond. …”
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2-sec-Butyl-1-(2-hydroxyethyl)-1H-benzimidazole-5-carboxylic acid
Published 2012“…In the title compound, C14H18N2O3, the carboxylic group is tilted by 12.00 (4)° with respect to the mean plane throught the benzimidazole ring system. The alcohol and carboxyl hydroxy groups are involved in intermolecular O-HO and O-HN hydrogen bonds, forming a two-dimensional network extending parallel the ab plane. …”
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Ethyl 1-(butan-2-yl)-2-(2-methoxyphenyl)- 1H-benzimidazole-5-carboxylate
Published 2011“…In the title compound, C21H24N2O3, the mean planes of the benzene ring and the benzimidazole ring system form a dihedral angle of 69.94 (7)�. The ethyl group atoms of the ethanoate fragment are disordered over two sets of sites, with refined occupancies of 0.742 (6) and 0.258 (6). …”
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S-Quinolin-2-ylmethyldithiocarbazate
Published 2007“…The planar quinoline ring system forms an angle of 67.7 (1) with the dithiocarbazate group. …”
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6-Cyanonaphthalen-2-yl 4-hexylbenzoate
Published 2014“…In the major disorder component, the naphthalene ring system forms a dihedral angle of 68.6 (5)° with the benzene ring. …”
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9-Benzyl-6-benzylsulfanyl-9H-purin-2-amine
Published 2014“…In the title compound, C19H17N5S, the dihedral angles between the purine ring system (r.m.s. deviation = 0.009 A°) and the S-bound and methylene-bound phenyl rings are 74.67 (8) and 71.28 (7)°, respectively. …”
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A free radical approach to ring-D aromatic steroids
Published 2008“…We proposed that the precursors 117a-d would lead to the 6,6,6,6 ring-D aromatic steroid ring system (such as that found in the natural product nicandrenone 67), via a cascade of radical ring-forming reactions. …”
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