Search Results - "NME"

A structural study of bis-(trimethylamine)alane, AlH3�2NMe3, by variable temperature X-ray crystallography and DFT calculations by Humphries, Terry, Sirsch, P., Decken, A., Sean McGrady, G.

“…The structure of AlH3·2NMe3 has been investigated by single-crystal X-ray diffraction over the range of 296-173 K. …”
Get full text

Transition metal diphenolate and dithiophenolate complexes as synthetic analogues of the active sites of nickel superoxide dismutase and galactose oxidase by Marshall, George

“…MRLoNMe (M= Ni; R = Cl, Br, Nap, tBu/Br) possess a reversible oxidation process assigned to the NiIII/NiII redox couple. …”
Get full text

Phase-field material point method for brittle fracture by Kakouris, Emmanouil, Triantafyllou, Savvas P.

Get full text

Hierarchical remeshing strategies with mesh mapping for topology optimisation by Panesar, Ajit, Brackett, David, Ashcroft, Ian, Wildman, Ricky D., Hague, Richard

Get full text

Commutativity of the strain energy density expression for the benefit of the FEM implementation of Koiter's initial postbuckling theory by Li, Shuguang, Yan, Jiayi, Zhang, Guofan, Duan, Shihui

Get full text

Deprotonation of large calixarenes-cation binding and conformations by Harrowfield, J., Koutsantonis, G., Ogden, Mark, Sobolev, A., White, A.

“…Single crystal X-ray studies of p-t-butylcalix[10]arene·2dmso·7H2O (1) and [NMe4][p-t-butylcalix[9]arene-H]·2dmso·H2O (2), provide new data on these large macrocycles and their conformations, that of 2 being the first where an encapsulated [NMe4]+ cation is present, while 1 contains the neutral ligand. …”
Get full text

Lewis base complexes of AlH3: Structural determination of monomeric and polymeric adducts by X-ray crystallography and DFT calculations by Humphries, Terry, Munroe, K., Decken, A., McGrady, G.

“…The AlH3 adducts of TMEDA (Me2NCH2CH 2NMe2), DIOX (O(CH2CH2) 2O), TEA (Et3N), BDMA (PhNMe2), and TMPDA (Me2NCH2CH2CH2NMe2) have each been characterised by single-crystal X-ray diffraction at low temperature, by 1H, 14N and 27Al NMR and FT-Raman and FT-IR spectroscopy, and by DFT calculations and elemental analysis. …”
Get full text

Lewis base complexes of AlH3: Prediction of preferred structure and stoichiometry by Humphries, Terry, Munroe, K., Decken, A., McGrady, G.

“…Raman spectroscopy and DFT calculations have been particularly helpful in elucidating the stoichiometric preferences of complexes that have been contentious; these include AlH3·NMe 2Et, AlH3·NMe3 and AlH 3·nEt2O. © The Royal Society of Chemistry 2013.…”
Get full text

Modelling fracture of aged graphite bricks under radiation and temperature by Hashim, Atheer, Kyaw, Si, Sun, Wei

Get full text

Synthesis, reactivity and preliminary biological activity of iron(0) complexes with cyclopentadienone and amino-appended N-heterocyclic carbene ligands by Cingolani, A., Zanotti, V., Zacchini, S., Massi, Max, Simpson, Peter, Maheshkumar Desai, N., Casari, I., Falasca, Marco, Rigamonti, L., Mazzoni, R.

“…Neutral and cationic cyclopentadienone (CpO) N-heterocyclic carbene (NHC) bis-carbonyl iron(0) complexes bearing, appended to the NHC ligand, either a terminal amino group on the lateral chain, [Fe(η 4 -CpO)(CO) 2 (κC-NHC(CH 2 ) n NH 2 )] with n = 2 (2a) and 3 (2b), or a cationic NMe 3+ fragment, [Fe(η 4 -CpO)(CO) 2 (κC-NHC(CH 2 ) 2 NMe 3 )](I) (3), were prepared and characterized in terms of their structure, stability and reactivity. …”
Get full text
Get full text

Synthesis, characterization, and reactivity studies of η 5 -cyclopentadienyliron dicarbonyl 4- (dimethylamino)phenyldiphenylphosphine iodide and di(µ2-chloro)(η 5 -cyclopentadienyl... by Tong, Yong Yao

“…A study on synthesis of new organometallic complexes, [CpFe(CO)2(PPh2(p-C6H4NMe2))]I (2) from the reactions of CpFe(CO)2I (1) with 4- (dimethylamino) phenyldiphenylphosphine via microwave-assisted reaction in toluene at 110 °C for 30 minutes. …”
Get full text
Get full text

Development of reusable electrochemical immunosensor for direct detection of biotin molecule / Khoo Mai Mai by Khoo, Mai Mai

“…In conclusion, the Ph-NH2/Ph-SO3-/Ph-NMe3+-fabricated immunosensor developed for biotin detection was found to be reproducible, selective, resistive to non-specific protein adsorption, stable, accurate and precise for the direct detection of biotin in food, and clinical samples. …”
Get full text
Get full text
Get full text

A finite strain Eulerian formulation for compressible and nearly incompressible hyperelasticity using high-order B-spline finite elements by Duddu, R., Lavier, L., Hughes, T., Calo, Victor

Get full text

On the computational efficiency of isogeometric methods for smooth elliptic problems using direct solvers by Collier, N., Dalcin, L., Calo, Victor

Get full text

Reactivity of the metalloligand [Pt2(µ-S)2(PPh3)4] toward tellurium(II) thiourea complexes: synthesis and structural characterization of the ditellurium(I) derivative [{Pt2(µ-S)2(P... by Fortney-Zirker, Ryland G., Henderson, William, Lane, Joseph R., Tiekink, Edward R. T. *

“…Likewise, attempted use of a fully substituted thiourea, viz. Me2NC(S)NMe2 (tmtu) in TeCl2(tmtu)2, also resulted in degradation of the {Pt2S2} core and detection of the known complex [(Ph3P)2PtCl{SC(NMe2)2}]+. …”
Get full text
Get full text

Regiospecific Formation and Unusual Optical Properties of 2, 5‐Bis (arylethynyl) rhodacyclopentadienes: A New Class of Luminescent Organometallics by Andreas, Steffen, Richard M, Ward, Meng Guan, Tay, Robert M, Edkins, Fabian, Seeler, Magda van, Leeuwen, Lars‐Olof, Pålsson, Andrew, Beeby, Andrei S, Batsanov, Judith AK, Howard, Todd B, Marder

“…A series of 2,5-bis(arylethynyl)rhodacyclopentadienes has been prepared by a rare example of regiospecific reductive coupling of 1,4-(p-R-phenyl)-1,3-butadiynes (R[DOUBLE BOND]H, Me, OMe, SMe, NMe2, CF3, CO2Me, CN, NO2, −C[TRIPLE BOND]C-(p-C6H4[BOND]NHex2), −C[TRIPLE BOND]C[BOND](p-C6H4[BOND]CO2Oct)) at [RhX(PMe3)4] (1) (X=−C[TRIPLE BOND]C[BOND]SiMe3 (a), −C[TRIPLE BOND]C-(p-C6H4[BOND]NMe2) (b), −C[TRIPLE BOND]C[BOND]C[TRIPLE BOND]C[BOND](p-C6H4[BOND]NPh2) (c) or [BOND]C[TRIPLE BOND]C[BOND]{p-C6H4-C[TRIPLE BOND]C[BOND](p-C6H4-N(C6H13)2)} (d) or Me (e)), giving the 2,5-bis(arylethynyl) isomer exclusively. …”
Get full text

Ru-based olefin metathesis catalysts bearing ph-responsive n-heterocyclic carbene (NHC) ligands: Activity control via degree of protonation by Balof, S., Yu, B., Lowe, Andrew, Ling, Y., Zhang, Y., Schanz, H.

“…Upon gradualprotonation of the NMe2 groups of the H2Tap ligand, the me-tathesis activity of both catalysts were gradually reduced dueto electronic changes of the N-heterocyclic carbene (NHC)ligand donor capability. …”
Get full text

Exploring sustainability in fluorine methodologies by Morgan, Patrick

“…A transfer fluorination reaction was developed through the treatment of [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)-RhCl] 22, and organic electrophiles in the absence of an external fluorine source, resulting in the formation of a bimetallic rhodacycle and a new fluorinated product. …”
Get full text

A novel design of an isochronous integration [iIntegration] framework for first/second order multidisciplinary transient systems by Shimada, Masao, Masuri, Siti Ujila, Tamma, Kumar K.

Get full text
Get full text

Molecular interactions of protein-based materials with ionic liquids by Muzammal, Shafaq

“…Two alanine based peptides, penta-alanine and deca-alanine, in addition to a peptide segment (ACE(leucine-aspargine-glycine-lysine-threonine-leucine-lysine-glycine)NME) from protein G in its non-standard form, were analysed for peptide-IL interactions in pure [C2C1Im][CH3CO2] IL and water. …”
Get full text