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    Production of mesoxalic acid from glycerol oxidation by laccase/2,2,6,6-tetramethylpiperidine-1-oxyl (LACASSE/TEMPO) system : effect of process parameters and kinetic study by Hong, Chi Shein

    Published 2016
    “…The study was conducted by reacting glycerol with TEMPO and laccase from Trametes versicolor and varying the reaction conditions such as temperature (5 °C - 61 °C), pH (3.50 - 6.15), molar ratio of glycerol to TEMPO (1:0 - 100:3) and ratio TEMPO to laccase (mM: U/mi) (9:0 - 9:4). A preliminary experiment in which the reaction conditions was fixed at 25 °C, pH 4.5, 10:3 of glycerol/TEMPO ratio and TEMPO/laccase ratio of 9:3 was conducted as screening before the investigation of reaction conditions on the oxidation products. …”
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