On-line preconcentration and cyclodextrin-modified micellar electrokinetic chromatography method for chiral separation of hexaconazole, penconazole and myclobutanil
A method for the on-line preconcentration and chiral separation of three chiral triazole fungicides, namely hexaconazole, penconazole and myclobutanil is reported. Simultaneous enantioseparation of the three triazole fungicides was successfully achieved by using CD-MEKC system containing 40 mM hydro...
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| Format: | Book Section |
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Faculty of Science, Universiti Teknologi Malaysia
2009
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| Online Access: | http://eprints.utm.my/9016/ |
| _version_ | 1848891790635040768 |
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| author | Wan Ibrahim, Wan Aini |
| author_facet | Wan Ibrahim, Wan Aini |
| author_sort | Wan Ibrahim, Wan Aini |
| building | UTeM Institutional Repository |
| collection | Online Access |
| description | A method for the on-line preconcentration and chiral separation of three chiral triazole fungicides, namely hexaconazole, penconazole and myclobutanil is reported. Simultaneous enantioseparation of the three triazole fungicides was successfully achieved by using CD-MEKC system containing 40 mM hydroxypropyl-γ-CD and 50 mM sodium dodecyl sulphate in 25 mM phosphate buffer (pH 3.0) solution. Stacking with a reverse migrating micelle (SRMM) and sweeping were used as two on-line preconcentration methods to enhance the concentration sensitivity. Results indicate that sweeping-CD-MEKC is better than SRMMCD-MEKC in terms of the sensitivity enhancement factor (SEF) of the three triazole fungicides. This is the first report on the simultaneous chiral separation of three triazole fungicides by on-line-CD-MEKC method. |
| first_indexed | 2025-11-15T21:03:34Z |
| format | Book Section |
| id | utm-9016 |
| institution | Universiti Teknologi Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-15T21:03:34Z |
| publishDate | 2009 |
| publisher | Faculty of Science, Universiti Teknologi Malaysia |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | utm-90162017-09-14T06:40:43Z http://eprints.utm.my/9016/ On-line preconcentration and cyclodextrin-modified micellar electrokinetic chromatography method for chiral separation of hexaconazole, penconazole and myclobutanil Wan Ibrahim, Wan Aini A method for the on-line preconcentration and chiral separation of three chiral triazole fungicides, namely hexaconazole, penconazole and myclobutanil is reported. Simultaneous enantioseparation of the three triazole fungicides was successfully achieved by using CD-MEKC system containing 40 mM hydroxypropyl-γ-CD and 50 mM sodium dodecyl sulphate in 25 mM phosphate buffer (pH 3.0) solution. Stacking with a reverse migrating micelle (SRMM) and sweeping were used as two on-line preconcentration methods to enhance the concentration sensitivity. Results indicate that sweeping-CD-MEKC is better than SRMMCD-MEKC in terms of the sensitivity enhancement factor (SEF) of the three triazole fungicides. This is the first report on the simultaneous chiral separation of three triazole fungicides by on-line-CD-MEKC method. Faculty of Science, Universiti Teknologi Malaysia 2009-05 Book Section PeerReviewed Wan Ibrahim, Wan Aini (2009) On-line preconcentration and cyclodextrin-modified micellar electrokinetic chromatography method for chiral separation of hexaconazole, penconazole and myclobutanil. In: Proceedings of Second International Conference and Workshops on Basic and Applied Sciences & Regional Annual Fundamental Science Seminar 2009. Faculty of Science, Universiti Teknologi Malaysia, . ISBN 978-983-9805-73-4 |
| spellingShingle | Wan Ibrahim, Wan Aini On-line preconcentration and cyclodextrin-modified micellar electrokinetic chromatography method for chiral separation of hexaconazole, penconazole and myclobutanil |
| title | On-line preconcentration and cyclodextrin-modified micellar electrokinetic chromatography method for chiral separation of hexaconazole, penconazole and myclobutanil |
| title_full | On-line preconcentration and cyclodextrin-modified micellar electrokinetic chromatography method for chiral separation of hexaconazole, penconazole and myclobutanil |
| title_fullStr | On-line preconcentration and cyclodextrin-modified micellar electrokinetic chromatography method for chiral separation of hexaconazole, penconazole and myclobutanil |
| title_full_unstemmed | On-line preconcentration and cyclodextrin-modified micellar electrokinetic chromatography method for chiral separation of hexaconazole, penconazole and myclobutanil |
| title_short | On-line preconcentration and cyclodextrin-modified micellar electrokinetic chromatography method for chiral separation of hexaconazole, penconazole and myclobutanil |
| title_sort | on-line preconcentration and cyclodextrin-modified micellar electrokinetic chromatography method for chiral separation of hexaconazole, penconazole and myclobutanil |
| url | http://eprints.utm.my/9016/ |