Simulation modeling of the phase behavior of palm oil-supercritical carbon dioxide

The phase behavior of crude palm oil (CPO) with supercritical CO2 was successfully modeled in an Aspen Plus® 10.2.1 commercial simulator (Aspen Technology Inc., Cambridge, MA) using the Redlich-Kwong-Aspen (RKA) equation of state thermodynamic model. The modeling procedure involved estimating pure...

Full description

Bibliographic Details
Main Authors: Lim, Chee Siang, Abd. Manan, Zainuddin, Sarmidi, Mohamad Roji
Format: Article
Language:English
Published: Springer Berlin / Heidelberg 2003
Subjects:
Online Access:http://eprints.utm.my/7554/
http://eprints.utm.my/7554/1/Mohamad_Roji_Sarmidi_2006_Simulation_Modeling_of_the_Phase.pdf
_version_ 1848891490273591296
author Lim, Chee Siang
Abd. Manan, Zainuddin
Sarmidi, Mohamad Roji
author_facet Lim, Chee Siang
Abd. Manan, Zainuddin
Sarmidi, Mohamad Roji
author_sort Lim, Chee Siang
building UTeM Institutional Repository
collection Online Access
description The phase behavior of crude palm oil (CPO) with supercritical CO2 was successfully modeled in an Aspen Plus® 10.2.1 commercial simulator (Aspen Technology Inc., Cambridge, MA) using the Redlich-Kwong-Aspen (RKA) equation of state thermodynamic model. The modeling procedure involved estimating pure component vapor pressures and critical properties and computing a regression of phase equilibrium behavior. The interaction parameters for the RKA model were obtained from the regression of experimental phase equilibrium data for a binary system of palm oil components-supercritical CO2 available in the literature. The distribution coefficients and solubilities of palm oil components obtained from this simulation showed good agreement with experimental data obtained from the literature. The model provides an efficient and cost-effective alternative for the preliminary design and optimization of a supercritical fluid extraction process involving a complex CPO-supercritical CO2 system.
first_indexed 2025-11-15T20:58:48Z
format Article
id utm-7554
institution Universiti Teknologi Malaysia
institution_category Local University
language English
last_indexed 2025-11-15T20:58:48Z
publishDate 2003
publisher Springer Berlin / Heidelberg
recordtype eprints
repository_type Digital Repository
spelling utm-75542017-10-11T01:28:32Z http://eprints.utm.my/7554/ Simulation modeling of the phase behavior of palm oil-supercritical carbon dioxide Lim, Chee Siang Abd. Manan, Zainuddin Sarmidi, Mohamad Roji TP Chemical technology The phase behavior of crude palm oil (CPO) with supercritical CO2 was successfully modeled in an Aspen Plus® 10.2.1 commercial simulator (Aspen Technology Inc., Cambridge, MA) using the Redlich-Kwong-Aspen (RKA) equation of state thermodynamic model. The modeling procedure involved estimating pure component vapor pressures and critical properties and computing a regression of phase equilibrium behavior. The interaction parameters for the RKA model were obtained from the regression of experimental phase equilibrium data for a binary system of palm oil components-supercritical CO2 available in the literature. The distribution coefficients and solubilities of palm oil components obtained from this simulation showed good agreement with experimental data obtained from the literature. The model provides an efficient and cost-effective alternative for the preliminary design and optimization of a supercritical fluid extraction process involving a complex CPO-supercritical CO2 system. Springer Berlin / Heidelberg 2003-11-23 Article PeerReviewed application/pdf en http://eprints.utm.my/7554/1/Mohamad_Roji_Sarmidi_2006_Simulation_Modeling_of_the_Phase.pdf Lim, Chee Siang and Abd. Manan, Zainuddin and Sarmidi, Mohamad Roji (2003) Simulation modeling of the phase behavior of palm oil-supercritical carbon dioxide. JAOCS, Journal of the American Oil Chemists' Society, 80 (11). pp. 1147-1156. ISSN 1558-9331 http://dx.doi.org/10.1007/s11746-003-0834-6 10.1007/s11746-003-0834-6
spellingShingle TP Chemical technology
Lim, Chee Siang
Abd. Manan, Zainuddin
Sarmidi, Mohamad Roji
Simulation modeling of the phase behavior of palm oil-supercritical carbon dioxide
title Simulation modeling of the phase behavior of palm oil-supercritical carbon dioxide
title_full Simulation modeling of the phase behavior of palm oil-supercritical carbon dioxide
title_fullStr Simulation modeling of the phase behavior of palm oil-supercritical carbon dioxide
title_full_unstemmed Simulation modeling of the phase behavior of palm oil-supercritical carbon dioxide
title_short Simulation modeling of the phase behavior of palm oil-supercritical carbon dioxide
title_sort simulation modeling of the phase behavior of palm oil-supercritical carbon dioxide
topic TP Chemical technology
url http://eprints.utm.my/7554/
http://eprints.utm.my/7554/
http://eprints.utm.my/7554/
http://eprints.utm.my/7554/1/Mohamad_Roji_Sarmidi_2006_Simulation_Modeling_of_the_Phase.pdf