Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide

Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation...

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Main Authors: Prasetyoko, Didik, Fansuri, Hamzah, Ramli, Zainab, Endud, Salasiah, Nur, Hadi
Format: Article
Published: Springer 2008
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Online Access:http://eprints.utm.my/7321/
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author Prasetyoko, Didik
Fansuri, Hamzah
Ramli, Zainab
Endud, Salasiah
Nur, Hadi
author_facet Prasetyoko, Didik
Fansuri, Hamzah
Ramli, Zainab
Endud, Salasiah
Nur, Hadi
author_sort Prasetyoko, Didik
building UTeM Institutional Repository
collection Online Access
description Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation of epoxide. Diol as a site-product was also observed due to the acidic properties of the catalysts.
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format Article
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institution Universiti Teknologi Malaysia
institution_category Local University
last_indexed 2025-11-15T20:58:05Z
publishDate 2008
publisher Springer
recordtype eprints
repository_type Digital Repository
spelling utm-73212011-04-22T02:20:02Z http://eprints.utm.my/7321/ Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide Prasetyoko, Didik Fansuri, Hamzah Ramli, Zainab Endud, Salasiah Nur, Hadi QD Chemistry Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation of epoxide. Diol as a site-product was also observed due to the acidic properties of the catalysts. Springer 2008 Article PeerReviewed Prasetyoko, Didik and Fansuri, Hamzah and Ramli, Zainab and Endud, Salasiah and Nur, Hadi (2008) Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide. Catalysis Letters . pp. 1-6. ISSN 1011-372X http://dx.doi.org/10.1007/s10562-008-9727-7 10.1007/s10562-008-9727-7
spellingShingle QD Chemistry
Prasetyoko, Didik
Fansuri, Hamzah
Ramli, Zainab
Endud, Salasiah
Nur, Hadi
Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide
title Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide
title_full Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide
title_fullStr Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide
title_full_unstemmed Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide
title_short Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide
title_sort tungsten oxides-containing titanium silicalite for liquid phase epoxidation of 1-octene with aqueous hydrogen peroxide
topic QD Chemistry
url http://eprints.utm.my/7321/
http://eprints.utm.my/7321/
http://eprints.utm.my/7321/