Fe(III)-salen encapsulated Al-MCM-41 as a catalyst in the polymerisation of bisphenol-A
Fe(III)-salen complexes encapsulated in the channels of Al-MCM-41 molecular sieves were successfully synthesised in situ by the flexible ligand method. The resulting compound was characterised by XRD, IR spectroscopy, nitrogen adsorption isotherm and 1H NMR techniques. The loading of complexes in Al...
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| Format: | Article |
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Elsevier
2005
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| Online Access: | http://eprints.utm.my/7298/ |
| _version_ | 1848891439934603264 |
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| author | Hamdan, Halimaton Navijanti, Vivin Nur, Hadi Muhid, Mohd Nazlan Mohd |
| author_facet | Hamdan, Halimaton Navijanti, Vivin Nur, Hadi Muhid, Mohd Nazlan Mohd |
| author_sort | Hamdan, Halimaton |
| building | UTeM Institutional Repository |
| collection | Online Access |
| description | Fe(III)-salen complexes encapsulated in the channels of Al-MCM-41 molecular sieves were successfully synthesised in situ by the flexible ligand method. The resulting compound was characterised by XRD, IR spectroscopy, nitrogen adsorption isotherm and 1H NMR techniques. The loading of complexes in Al-MCM-41 depends on the quantity of framework aluminium, suggesting that there is an electrostatic interaction between the positive charges of the encapsulated Fe(III)-salen complexes and the negative charges of the Al-MCM-41 framework. Polymerisation of bisphenol-A catalysed by Fe(III)-salen-Al-MCM-41 gave 67% conversion; significantly higher than the conventional homogeneous Fe(III)-salen catalyst. |
| first_indexed | 2025-11-15T20:58:00Z |
| format | Article |
| id | utm-7298 |
| institution | Universiti Teknologi Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-15T20:58:00Z |
| publishDate | 2005 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | utm-72982009-01-01T06:44:04Z http://eprints.utm.my/7298/ Fe(III)-salen encapsulated Al-MCM-41 as a catalyst in the polymerisation of bisphenol-A Hamdan, Halimaton Navijanti, Vivin Nur, Hadi Muhid, Mohd Nazlan Mohd TP Chemical technology Fe(III)-salen complexes encapsulated in the channels of Al-MCM-41 molecular sieves were successfully synthesised in situ by the flexible ligand method. The resulting compound was characterised by XRD, IR spectroscopy, nitrogen adsorption isotherm and 1H NMR techniques. The loading of complexes in Al-MCM-41 depends on the quantity of framework aluminium, suggesting that there is an electrostatic interaction between the positive charges of the encapsulated Fe(III)-salen complexes and the negative charges of the Al-MCM-41 framework. Polymerisation of bisphenol-A catalysed by Fe(III)-salen-Al-MCM-41 gave 67% conversion; significantly higher than the conventional homogeneous Fe(III)-salen catalyst. Elsevier 2005-02 Article PeerReviewed Hamdan, Halimaton and Navijanti, Vivin and Nur, Hadi and Muhid, Mohd Nazlan Mohd (2005) Fe(III)-salen encapsulated Al-MCM-41 as a catalyst in the polymerisation of bisphenol-A. Solid State Sciences, 7 (2). pp. 239-244. ISSN 1293-2558 http://dx.doi.org/10.1016/j.solidstatesciences.2004.10.042 10.1016/j.solidstatesciences.2004.10.042 |
| spellingShingle | TP Chemical technology Hamdan, Halimaton Navijanti, Vivin Nur, Hadi Muhid, Mohd Nazlan Mohd Fe(III)-salen encapsulated Al-MCM-41 as a catalyst in the polymerisation of bisphenol-A |
| title | Fe(III)-salen encapsulated Al-MCM-41 as a catalyst in the polymerisation of bisphenol-A
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| title_full | Fe(III)-salen encapsulated Al-MCM-41 as a catalyst in the polymerisation of bisphenol-A
|
| title_fullStr | Fe(III)-salen encapsulated Al-MCM-41 as a catalyst in the polymerisation of bisphenol-A
|
| title_full_unstemmed | Fe(III)-salen encapsulated Al-MCM-41 as a catalyst in the polymerisation of bisphenol-A
|
| title_short | Fe(III)-salen encapsulated Al-MCM-41 as a catalyst in the polymerisation of bisphenol-A
|
| title_sort | fe(iii)-salen encapsulated al-mcm-41 as a catalyst in the polymerisation of bisphenol-a |
| topic | TP Chemical technology |
| url | http://eprints.utm.my/7298/ http://eprints.utm.my/7298/ http://eprints.utm.my/7298/ |