Determination of carotene, tocopherols and tocotrienols in residue oil from palm pressed fiber using pressurized liquid extraction-normal phase liquid chromatography

Pressurized liquid extraction (PLE) along with normal phase liquid chromatography (NPLC) is evaluated as a new approach for the determination of -carotene and Vitamin E isomers in residue oil obtained from palm pressed fiber (PPF). The relative extraction recoveries obtained by optimized PLE were fo...

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Main Authors: Sanagi, M. Marsin, See, H.H., Wan Ibrahim, Wan Aini, Abu Naim, Ahmedy
Format: Article
Language:English
Published: Elsevier B.V. 2005
Subjects:
Online Access:http://eprints.utm.my/7106/
http://eprints.utm.my/7106/1/MARLINA_MMSanagi2005_DeterminationOfCaroteneTocopherolsAndTocotrienols.pdf
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author Sanagi, M. Marsin
See, H.H.
Wan Ibrahim, Wan Aini
Abu Naim, Ahmedy
author_facet Sanagi, M. Marsin
See, H.H.
Wan Ibrahim, Wan Aini
Abu Naim, Ahmedy
author_sort Sanagi, M. Marsin
building UTeM Institutional Repository
collection Online Access
description Pressurized liquid extraction (PLE) along with normal phase liquid chromatography (NPLC) is evaluated as a new approach for the determination of -carotene and Vitamin E isomers in residue oil obtained from palm pressed fiber (PPF). The relative extraction recoveries obtained by optimized PLE were found to be equivalent (~100%) to conventional Soxhlet extraction. Optimized PLE was obtained (5 g of sample, 80 ◦C, 1500 psi, 2× 10 min static extractions with flush volume 50%) combined with NPLC system. Typical extractions give 3.7–4.0 mg ml-1 of Vitamin E isomers and -carotene of 3.3–3.5 mg ml-1, which is similar to or greater than classical Soxhlet extraction with n-hexane or chloroform. The new developed method demonstrated an acceptable performance with good efficiency in terms of total extraction time, total solvent usage, total -carotene and Vitamin E isomers contents as well as exceptional method repeatability. © 2005 Published by Elsevier B.V.
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spelling utm-71062010-06-01T15:49:20Z http://eprints.utm.my/7106/ Determination of carotene, tocopherols and tocotrienols in residue oil from palm pressed fiber using pressurized liquid extraction-normal phase liquid chromatography Sanagi, M. Marsin See, H.H. Wan Ibrahim, Wan Aini Abu Naim, Ahmedy QD Chemistry Pressurized liquid extraction (PLE) along with normal phase liquid chromatography (NPLC) is evaluated as a new approach for the determination of -carotene and Vitamin E isomers in residue oil obtained from palm pressed fiber (PPF). The relative extraction recoveries obtained by optimized PLE were found to be equivalent (~100%) to conventional Soxhlet extraction. Optimized PLE was obtained (5 g of sample, 80 ◦C, 1500 psi, 2× 10 min static extractions with flush volume 50%) combined with NPLC system. Typical extractions give 3.7–4.0 mg ml-1 of Vitamin E isomers and -carotene of 3.3–3.5 mg ml-1, which is similar to or greater than classical Soxhlet extraction with n-hexane or chloroform. The new developed method demonstrated an acceptable performance with good efficiency in terms of total extraction time, total solvent usage, total -carotene and Vitamin E isomers contents as well as exceptional method repeatability. © 2005 Published by Elsevier B.V. Elsevier B.V. 2005-02-08 Article PeerReviewed application/pdf en http://eprints.utm.my/7106/1/MARLINA_MMSanagi2005_DeterminationOfCaroteneTocopherolsAndTocotrienols.pdf Sanagi, M. Marsin and See, H.H. and Wan Ibrahim, Wan Aini and Abu Naim, Ahmedy (2005) Determination of carotene, tocopherols and tocotrienols in residue oil from palm pressed fiber using pressurized liquid extraction-normal phase liquid chromatography. Analytica Chimica Acta, 538 (71-76). ISSN 0003-2670 http://dx.doi.org/10.1016/j.aca.2005.02.028 10.1016/j.aca.2005.02.028
spellingShingle QD Chemistry
Sanagi, M. Marsin
See, H.H.
Wan Ibrahim, Wan Aini
Abu Naim, Ahmedy
Determination of carotene, tocopherols and tocotrienols in residue oil from palm pressed fiber using pressurized liquid extraction-normal phase liquid chromatography
title Determination of carotene, tocopherols and tocotrienols in residue oil from palm pressed fiber using pressurized liquid extraction-normal phase liquid chromatography
title_full Determination of carotene, tocopherols and tocotrienols in residue oil from palm pressed fiber using pressurized liquid extraction-normal phase liquid chromatography
title_fullStr Determination of carotene, tocopherols and tocotrienols in residue oil from palm pressed fiber using pressurized liquid extraction-normal phase liquid chromatography
title_full_unstemmed Determination of carotene, tocopherols and tocotrienols in residue oil from palm pressed fiber using pressurized liquid extraction-normal phase liquid chromatography
title_short Determination of carotene, tocopherols and tocotrienols in residue oil from palm pressed fiber using pressurized liquid extraction-normal phase liquid chromatography
title_sort determination of carotene, tocopherols and tocotrienols in residue oil from palm pressed fiber using pressurized liquid extraction-normal phase liquid chromatography
topic QD Chemistry
url http://eprints.utm.my/7106/
http://eprints.utm.my/7106/
http://eprints.utm.my/7106/
http://eprints.utm.my/7106/1/MARLINA_MMSanagi2005_DeterminationOfCaroteneTocopherolsAndTocotrienols.pdf