Structural synthesis and modification of zeolite as methane adsorbent

Improvements in the technologies for the synthesis of zeolites and development of zeolite with different pore sizes hold a great promise in the chemical and petrochemical industries. Adsorption of methane in porous materials such as zeolite offers a possibility of storing methane at low pressure wit...

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Main Authors: Nor Kamarudin, Khairul Sozana, Mat, Hanapi, Hamdan, Halimaton
Format: Article
Language:English
Published: 2003
Subjects:
Online Access:http://eprints.utm.my/547/
http://eprints.utm.my/547/1/KhairulSozana2003_StructuralSynthesis_and_ModificationOfZeolite.pdf
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author Nor Kamarudin, Khairul Sozana
Mat, Hanapi
Hamdan, Halimaton
author_facet Nor Kamarudin, Khairul Sozana
Mat, Hanapi
Hamdan, Halimaton
author_sort Nor Kamarudin, Khairul Sozana
building UTeM Institutional Repository
collection Online Access
description Improvements in the technologies for the synthesis of zeolites and development of zeolite with different pore sizes hold a great promise in the chemical and petrochemical industries. Adsorption of methane in porous materials such as zeolite offers a possibility of storing methane at low pressure with high capacity. In this research, zeolite X (Y) have been hydrothermally synthesized in the laboratory with different composition (6.4Na2O: Al2O3: xSiO: 180H2O, 2 < x <20) followed by characterization procedure using XRD method and BET surface analyser. Post synthesis or modification using cation exchange technique has been carried out to observe the effect different cation (Li, K, Ca, Mg) on zeolite’s properties. Zeolites with faujasite type of framework were produced with different relative crystallinity and surface area. The surface area of exchanged zeolite varied depending on cation types and groups. Molecular simulation was also carried out to determine surface area of zeolites and followed by methane adsorption at 273K and 100kPa. Result shows that cation exchange modification can increase the surface area, hence increase methane adsorption.
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spelling utm-5472017-09-06T06:37:16Z http://eprints.utm.my/547/ Structural synthesis and modification of zeolite as methane adsorbent Nor Kamarudin, Khairul Sozana Mat, Hanapi Hamdan, Halimaton TP Chemical technology Improvements in the technologies for the synthesis of zeolites and development of zeolite with different pore sizes hold a great promise in the chemical and petrochemical industries. Adsorption of methane in porous materials such as zeolite offers a possibility of storing methane at low pressure with high capacity. In this research, zeolite X (Y) have been hydrothermally synthesized in the laboratory with different composition (6.4Na2O: Al2O3: xSiO: 180H2O, 2 < x <20) followed by characterization procedure using XRD method and BET surface analyser. Post synthesis or modification using cation exchange technique has been carried out to observe the effect different cation (Li, K, Ca, Mg) on zeolite’s properties. Zeolites with faujasite type of framework were produced with different relative crystallinity and surface area. The surface area of exchanged zeolite varied depending on cation types and groups. Molecular simulation was also carried out to determine surface area of zeolites and followed by methane adsorption at 273K and 100kPa. Result shows that cation exchange modification can increase the surface area, hence increase methane adsorption. 2003 Article NonPeerReviewed application/pdf en http://eprints.utm.my/547/1/KhairulSozana2003_StructuralSynthesis_and_ModificationOfZeolite.pdf Nor Kamarudin, Khairul Sozana and Mat, Hanapi and Hamdan, Halimaton (2003) Structural synthesis and modification of zeolite as methane adsorbent. Proceeding of Annual Fundamental Science Seminar, 2003 . (Unpublished)
spellingShingle TP Chemical technology
Nor Kamarudin, Khairul Sozana
Mat, Hanapi
Hamdan, Halimaton
Structural synthesis and modification of zeolite as methane adsorbent
title Structural synthesis and modification of zeolite as methane adsorbent
title_full Structural synthesis and modification of zeolite as methane adsorbent
title_fullStr Structural synthesis and modification of zeolite as methane adsorbent
title_full_unstemmed Structural synthesis and modification of zeolite as methane adsorbent
title_short Structural synthesis and modification of zeolite as methane adsorbent
title_sort structural synthesis and modification of zeolite as methane adsorbent
topic TP Chemical technology
url http://eprints.utm.my/547/
http://eprints.utm.my/547/1/KhairulSozana2003_StructuralSynthesis_and_ModificationOfZeolite.pdf