The characterization of Ni-based catalysts for autothermal reforming process
A simple technique approach was used to characterize the structural and chemical properties of CoO-NiO catalysts supported on delta-Al2O3, HZSM-5 and MgO-Al2O3.The morphology of the catalysts was studied by X-Ray diffraction to determine the phase composition and the particle size of the catalysts....
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| Format: | Article |
| Language: | English |
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Universiti Teknologi Petronas
2004
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| Online Access: | http://eprints.utm.my/5138/ http://eprints.utm.my/5138/1/M.H.A.Latiff2004_TheCharacterizationOfNi-basedCatalysts.pdf |
| _version_ | 1848890981804408832 |
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| author | Latiff, M. H. A. Songip, Ahmad Rahman Nasri, N. S. Tutuk, D. K. |
| author_facet | Latiff, M. H. A. Songip, Ahmad Rahman Nasri, N. S. Tutuk, D. K. |
| author_sort | Latiff, M. H. A. |
| building | UTeM Institutional Repository |
| collection | Online Access |
| description | A simple technique approach was used to characterize the structural and chemical properties of CoO-NiO catalysts supported on delta-Al2O3, HZSM-5 and MgO-Al2O3.The morphology of the catalysts was studied by X-Ray diffraction to determine the phase composition and the particle size of the catalysts. Temperature-programmed reduction (TPR) reveals the formation of NiO and Co3O4 in dependence on temperature in case of catalysts supported on delta-Al2O3 and MgO-Al2O3 at higher metal loading. The catalysts
supported on HZSM-5 also show appearance of NiO, CoO and Co3O4, which could lead to deactivation of the catalysts via formation of coke on the catalyst surface. The formation of NiO-CoO-MgO solid solution supported on MgO-Al2O3 exhibited stronger interaction between metal and support thus can make the catalysts more resistant to sintering and enhance the structure durability of catalyst in high temperature methane reforming process. |
| first_indexed | 2025-11-15T20:50:43Z |
| format | Article |
| id | utm-5138 |
| institution | Universiti Teknologi Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T20:50:43Z |
| publishDate | 2004 |
| publisher | Universiti Teknologi Petronas |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | utm-51382010-06-01T03:23:50Z http://eprints.utm.my/5138/ The characterization of Ni-based catalysts for autothermal reforming process Latiff, M. H. A. Songip, Ahmad Rahman Nasri, N. S. Tutuk, D. K. T Technology (General) A simple technique approach was used to characterize the structural and chemical properties of CoO-NiO catalysts supported on delta-Al2O3, HZSM-5 and MgO-Al2O3.The morphology of the catalysts was studied by X-Ray diffraction to determine the phase composition and the particle size of the catalysts. Temperature-programmed reduction (TPR) reveals the formation of NiO and Co3O4 in dependence on temperature in case of catalysts supported on delta-Al2O3 and MgO-Al2O3 at higher metal loading. The catalysts supported on HZSM-5 also show appearance of NiO, CoO and Co3O4, which could lead to deactivation of the catalysts via formation of coke on the catalyst surface. The formation of NiO-CoO-MgO solid solution supported on MgO-Al2O3 exhibited stronger interaction between metal and support thus can make the catalysts more resistant to sintering and enhance the structure durability of catalyst in high temperature methane reforming process. Universiti Teknologi Petronas 2004 Article PeerReviewed application/pdf en http://eprints.utm.my/5138/1/M.H.A.Latiff2004_TheCharacterizationOfNi-basedCatalysts.pdf Latiff, M. H. A. and Songip, Ahmad Rahman and Nasri, N. S. and Tutuk, D. K. (2004) The characterization of Ni-based catalysts for autothermal reforming process. Proceedings of 18th Symposium of Malaysian Chemical Engineers SOMChE 2004, 1 . pp. 1-79. |
| spellingShingle | T Technology (General) Latiff, M. H. A. Songip, Ahmad Rahman Nasri, N. S. Tutuk, D. K. The characterization of Ni-based catalysts for autothermal reforming process |
| title | The characterization of Ni-based catalysts for autothermal reforming process |
| title_full | The characterization of Ni-based catalysts for autothermal reforming process |
| title_fullStr | The characterization of Ni-based catalysts for autothermal reforming process |
| title_full_unstemmed | The characterization of Ni-based catalysts for autothermal reforming process |
| title_short | The characterization of Ni-based catalysts for autothermal reforming process |
| title_sort | characterization of ni-based catalysts for autothermal reforming process |
| topic | T Technology (General) |
| url | http://eprints.utm.my/5138/ http://eprints.utm.my/5138/1/M.H.A.Latiff2004_TheCharacterizationOfNi-basedCatalysts.pdf |