Hydroxyl group studies by FTIR and catalytic activity of dealuminated ZSM-5 zeolite for ethylene conversion

The hydroxyl groups of ZSM-5 and dealuminated ZSM-5 zeolites can be determine by FT-IR spectroscopy technique. All zeolites are having three types of hydroxyl group, i.e. terminal silanol and site defect (3744 cm(-1)), non-framework aluminium (3699 cm(-1)), and framework aluminium (3609 cm(-1)). Int...

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Main Authors: Anggoro, Didi Dwi, Saidina Amin, Nor Aishah
Format: Article
Language:English
Published: Faculty of Chemical and Natural Resources Engineering, UTM 2001
Subjects:
Online Access:http://eprints.utm.my/4973/
http://eprints.utm.my/4973/1/DidiDwiAnggoro2001_HydroxylGroupStudiesByFTIR.pdf
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author Anggoro, Didi Dwi
Saidina Amin, Nor Aishah
author_facet Anggoro, Didi Dwi
Saidina Amin, Nor Aishah
author_sort Anggoro, Didi Dwi
building UTeM Institutional Repository
collection Online Access
description The hydroxyl groups of ZSM-5 and dealuminated ZSM-5 zeolites can be determine by FT-IR spectroscopy technique. All zeolites are having three types of hydroxyl group, i.e. terminal silanol and site defect (3744 cm(-1)), non-framework aluminium (3699 cm(-1)), and framework aluminium (3609 cm(-1)). Intensity of 3609 cm(-1), and 3744 cm(-1) bands of dealuminated ZSM-5 zeolites are decreases. Dealumination of ZSM-5 increases ethylene conversion but decreases gasoline selectivity. The amount of aluminium in the zeolite framework and purity of zeolite has a role in the ethylene conversion to liquid hydrocarbons process.
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publisher Faculty of Chemical and Natural Resources Engineering, UTM
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spelling utm-49732010-06-01T03:22:23Z http://eprints.utm.my/4973/ Hydroxyl group studies by FTIR and catalytic activity of dealuminated ZSM-5 zeolite for ethylene conversion Anggoro, Didi Dwi Saidina Amin, Nor Aishah T Technology (General) The hydroxyl groups of ZSM-5 and dealuminated ZSM-5 zeolites can be determine by FT-IR spectroscopy technique. All zeolites are having three types of hydroxyl group, i.e. terminal silanol and site defect (3744 cm(-1)), non-framework aluminium (3699 cm(-1)), and framework aluminium (3609 cm(-1)). Intensity of 3609 cm(-1), and 3744 cm(-1) bands of dealuminated ZSM-5 zeolites are decreases. Dealumination of ZSM-5 increases ethylene conversion but decreases gasoline selectivity. The amount of aluminium in the zeolite framework and purity of zeolite has a role in the ethylene conversion to liquid hydrocarbons process. Faculty of Chemical and Natural Resources Engineering, UTM 2001 Article PeerReviewed application/pdf en http://eprints.utm.my/4973/1/DidiDwiAnggoro2001_HydroxylGroupStudiesByFTIR.pdf Anggoro, Didi Dwi and Saidina Amin, Nor Aishah (2001) Hydroxyl group studies by FTIR and catalytic activity of dealuminated ZSM-5 zeolite for ethylene conversion. Proceedings of The 15th Symposium of Malaysian Chemical Engineers SOMChE 2001 . pp. 58-63.
spellingShingle T Technology (General)
Anggoro, Didi Dwi
Saidina Amin, Nor Aishah
Hydroxyl group studies by FTIR and catalytic activity of dealuminated ZSM-5 zeolite for ethylene conversion
title Hydroxyl group studies by FTIR and catalytic activity of dealuminated ZSM-5 zeolite for ethylene conversion
title_full Hydroxyl group studies by FTIR and catalytic activity of dealuminated ZSM-5 zeolite for ethylene conversion
title_fullStr Hydroxyl group studies by FTIR and catalytic activity of dealuminated ZSM-5 zeolite for ethylene conversion
title_full_unstemmed Hydroxyl group studies by FTIR and catalytic activity of dealuminated ZSM-5 zeolite for ethylene conversion
title_short Hydroxyl group studies by FTIR and catalytic activity of dealuminated ZSM-5 zeolite for ethylene conversion
title_sort hydroxyl group studies by ftir and catalytic activity of dealuminated zsm-5 zeolite for ethylene conversion
topic T Technology (General)
url http://eprints.utm.my/4973/
http://eprints.utm.my/4973/1/DidiDwiAnggoro2001_HydroxylGroupStudiesByFTIR.pdf